Answer:
The molecular formula = 
Explanation:
Given that:
Mass of compound, m = 0.145 g
Temperature = 200 °C
The conversion of T( °C) to T(K) is shown below:
T(K) = T( °C) + 273.15
So,
T = (200 + 273.15) K = 473.15 K
V = 97.2 mL = 0.0972 L
Pressure = 0.74 atm
Considering,
Using ideal gas equation as:
where,
P is the pressure
V is the volume
m is the mass of the gas
M is the molar mass of the gas
T is the temperature
R is Gas constant having value = 0.0821 L.atm/K.mol
Applying the values in the above equation as:-
The empirical formula is =
Molecular formulas is the actual number of atoms of each element in the compound while empirical formulas is the simplest or reduced ratio of the elements in the compound.
Thus,
Molecular mass = n × Empirical mass
Where, n is any positive number from 1, 2, 3...
Mass from the Empirical formula = 12 + 1 = 13 g/mol
Molar mass = 78.31 g/mol
So,
Molecular mass = n × Empirical mass
78.31 = n × 13
⇒ n ≅ 6
The molecular formula = 
Explanation:
Copper sulphate reacts with potassium iodide to form cuprous iodide and iodine.
2CuSO
4
+4KI→Cu
2
I
2
↓+I
2
+2K
2
SO
4
Thus, CuI
2
is not formed in this reaction.
Hence, the option B is incorrect and option A is correct.
The liberated iodine is titrated with sodium thiosulphate to form sodium tetrathionate.
2Na
2
S
2
O
3
+I
2
→Na
2
S
4
O
6
+2NaI
Iodine is reduced and sodium thiosulphate is oxidized.
The easiest way is to use the Law of Gay-Lussac. This law states that there is a direct relation between the temperature in Kelvin of a gas and the pressure.
Then, namig p the pressure and T the temperature in Kelvin and using subscripts for every state:
p/T is constant ==> p_1 / T_1 = p_2/T_2
From which you obtain:
p_2 = [p_1 / T_1] * T_2
T_1 = 33.0 + 273.15 = 306.15 K
T _2 = 21.4 + 273.15 = 294.55 K
p_1 = 1014 kPa
p_2 = 1014 kPa * 294.55 K / 306.15 K = 975.6 kPa