Answer:
Option (2) 2
Explanation:
NO3- + 4H+ + Pb → Pb2+ + NO2 + 2H2O
The equation above can be balance as follow:
There are 3 atoms of the left side and a total of 4 atoms on the right side. It can be balance by putting 2 in front NO3- and 2 in front of NO2 as shown below:
2NO3- + 4H+ + Pb → Pb2+ + 2NO2 + 2H2O
Now the equation is balanced.
The coefficient of NO2 is 2
Answer:
volume is 7.0 liters
Explanation:
We are given;
- Molarity of the aqueous solution as 2.0 M
- Moles of the solute, K₂S as 14 moles
We are required to determine the volume of the solution;
We need to know that;
Molarity = Moles ÷ volume
Therefore;
Volume = Moles ÷ Molarity
Thus;
Volume of the solution = 14 moles ÷ 2.0 M
= 7.0 L
Hence, the volume of the molar solution is 7.0 L
Mass is the property of a physical body and the resistance to acceleration when a net force is applied on the body.
The atomic mass of sodium (Na) is = 22.98
The atomic mass of nitrate (N) is = 14.00
The atomic mass of oxygen (O) is = 15.99
The sodium nitrate (NaNO3) consists of the atomic masses of Na+N+(O)3 = 85 grams
Therefore, the mass of 6.5 mol of sodium nitrate is = 6.5 * 1 mol of NaNO3
= 6.5 * (85)
= 552.50 grams
Answer : The correct answer for a) 4-bromo-2-iodo-4-methyl pentane and b)5-bromo-2-ethoxy-2-methyl pentane.
A) Reaction with NaI :
Reaction of alkyl halide with NaI is known as Finkelstein Reaction . The acetone is used as solvent . It involves bimolecular nucleophillic substitution rmechanism (SN²) . There is replecement of one halogen with other occurs .
The incoming Nucleophile(Nu⁻) (halide) attacks on carbon from back side , while the leaving group (halide) leaves the compound from front side , simultaneously. The product so formed have is inverted .(Image)
NaI releases I⁻ ion which act as nucelophile and attacks on C1 carbon and Br⁻ from C1 carbon is released . Out of two bromines at C1 and C4 carbons , C1 is primary carbon which is less sterically hindered while C-4 is tertiary carbon and sterically hindered . So it is easy for incoming Nu⁻ to attack on C1 carbon .So Br⁻ is repleaced by I⁻.
1,4-dibromo-4-methylpentane + NaI → 4-bromo-1-iodo-4-methylpentane
The product formed from reaction between 1,4-dibromo-4-methylpentane and NaI is 4-bromo-1-iodo-4-methylpentane . (Image)
B) Reaction with AgNO3 :
Reaction of alkyl halide with AgNO3 in ethanol takes place via SN¹ ( unimolecular nucleophilic substitution ) mechanism . In this leaving group(halide) leaves from alkyl halide forming an intermediate carbocation species . The incoming Nu⁻ attack on this carbocation.
AgNO3 reacts releases Ag⁺ion which abstract Br⁻ of C-4 carbon from 1,4-dibromo-4-methylpentane. THis forms tertiary carbocation which is more stable than carbocation formed by removal of Br from C-1 . The ethanol being more Nucleophilic than NO₃⁻ (from AgNO₃), attacks on this carbocation .(Image )
The product formed as a result is 5-bromo-2-ethoxy-2-methyl pentane.