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Drupady [299]
3 years ago
14

A ketone and a Grignard reagent react in ether solution followed by acid workup, to form a tertiary alcohol. Grignard reactions

must be scrupulously dry in order to work effectively. A common method of drying glassware is to rinse with acetone prior to use.
1. Why is rinsing with acetone not suitable for the reaction stated in the question?a)Magnesium does not dissolve in acetone.b)Water dissolves in acetone. Adding acetone will add water to the reaction flask.c)Magnesium dissolves in acetone. Adding acetone will remove a vital reactant from the flask.d)Acetone is a ketone. Grignard reagents will react with acetone to make an unwanted byproduct.
Chemistry
1 answer:
Gekata [30.6K]3 years ago
6 0

Answer:The correct answer is "d"

Explanation:

Grignard reagent has a tendency to react with ketones.This reaction involves affect by the nucleophilic carbon atom present in the grignard reagent at carbonyl carbon atom to form a new C-C bond.Acidic work up converts the alkaloid species into corresponding alcohol,in this case mostly likely tertiary alcohol.

Mostly its is preferred to oven-dry all glasswares prior to starting experiment, at temperature above 100°C.

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The sulfur atom of sulfur dioxide is considered to be sp2-hybridized. The expected bond angle is 120°, but is actually slightly
Alja [10]

Answer: The bonds are intermediate between double and single bonds

Explanation:

A closer look at the diagram below shows that the bonds in sulphur IV oxide are intermediate between double and single bonds. Hence they do not have the exact bond angle of single bonds. This is why the bond angle is not exactly 120°. There are two resonance structures in the diagram that clearly show this point.

6 0
3 years ago
A chemical equilibrium between gaseous reactants and products is shown.
fenix001 [56]

Explanation:

Question 1:

It will shift toward the reactant side as there are a greater number of moles of gas on the reactant side.

Pressure changes only affects only equilibrium involving a gas or gases. An increase in pressure shifts the equilibrium in the direction of the reaction with lower volume.

                 N₂  + 3H₂   ⇆   2NH₃

                        4                  2

An increase in pressure will shift the equilibrium towards the product side.

If the pressure is decreased, equilibrium will shifts towards the side of the reactants. This is because the volume of the reactants are higher than that of the product.

Question 2:

True

Based on Le Chatelier's principle, an increase in temperature will shift the equilibrium position towards the products in an endothermic reaction.

An endothermic reaction is a reaction that absorbs heat from the surroundings.

A rise in temperature shifts equilibrium position to the direction that absorbs the heat and vice versa.

In an endothermic reaction, the forward reaction absorbs the heat and therefore equilibrium shifts towards the side of product.

Question 3:

Decreasing the pressure              A) Shift to the left

Adding hydrogen gas                   B) Shift to the right

Adding a catalyst                          C) No effect

                N₂  + 3H₂   ⇆   2NH₃

Pressure : Decreasing the pressure will shift the equilibrium position to the left. In reactions involving gases, increase in pressure favors the side with a lesser volume. An increase in pressure will favor the formation of ammonia as a product.

A decrease in pressure shifts the equilibrium to the left towards the side of high volume.

Concentration: addition of hydrogen gas will increase the concentration of the gas. An increase in concentration favors the side that uses up the specie and lowers it concentration.

If the concentration of hydrogen gas is increased the equilibrium will shift to the right to annul the concentration of reactants that has increased.

Catalyst: Catalysts have no effect on the position of chemical equilibrium. It only affects the rate at which equilibrium can be reached.

Question 4:

Adding more of gas C to the system

The change that would shift the equilibrium system to the left is by adding more of gas C to the system.

This will increase the concentration of gas C, in order to annul this, the equilibrium will shift to the left.

  • Heating the system will shift the equilibrium to the right
  • Increasing volume only affects purely gaseous reactions.
  • Removing some of gas C from the system shifts the equilibrium to the right.

Question 5:

Heating the system

This is an exothermic reaction because enthalpy change is negative. A rise in temperature shifts equilibrium position to the direction that absorbs heat.

In an exothermic reaction, heat is given off in the forward process. The reverse process is endothermic and heat is absorbed.

Therefore, heating the system will shift the equilibrium to the left and heat is absorbed.

Question 6:

This reaction is exothermic because the system shifted to the left on heating.

It is right to conclude that this reaction is exothermic because the system shifted to the left on heating .

Since the reaction turned dark brown on heating, it shows that more of the reactant Nitrogen dioxide gas was produced.

We can see that the reaction is exothermic in the forward process. An increase in temperature shifts equilibrium position backward to the side that absorbs the heat. This allows for the production of more nitrogen dioxide.

Question 7:

Shift it toward the reactants

A decrease in the concentration of the reactants shift the reaction towards the sides of the reactants.

An increase in concentration of a specie favors the direction that uses up that specie and lowers its concentration.

If the concentration of a specie on the reactant side is increased, equilibrium shifts to the right where more products are formed.

if we decrease the concentration of reactants, the products will be more concentrated and the equilibrium will shift to the left i.e the reactant side.

Learn more:

Equilibrium constant brainly.com/question/11126965

#learnwithBrainly

3 0
4 years ago
C3H8+3O2 = 3CO2+4H2O what is the enthalpy combustion please show work
irakobra [83]

Answer:

\Delta H_{comb}=2043.85kJ/mol

Explanation:

Hello there!

In this case, according to the given chemical reaction, it possible for us to set up the expression for the calculation of the enthalpy change as shown below:

\Delta H_r=-\Delta H_{comb}=3\Delta _fH_{CO_2}+4\Delta _fH_{H_2O}-\Delta _fH_{C_3H_8}-3\Delta _fH_{O_2}

Thus, given the values of the enthalpies of formation on the attached file, we obtain:-\Delta H_{comb}=3(-393.5kJ/mol)+4(-241.8kJ/mol)-(-103.85kJ/mol)-3(0kJ/mol)\\\\-\Delta H_{comb}=-2043.85kJ/mol\\\\\Delta H_{comb}=2043.85kJ/mol

Best regards!

5 0
3 years ago
Which of the following is an example of climate?
Svetach [21]
"<span>A. The polar regions have long winters and short, cool summers." would be the correct answer.
</span>
7 0
3 years ago
Read 2 more answers
Initial temperature of water (oC)
Ilia_Sergeevich [38]
The burning point of water in Celsius or the cooling point?
5 0
4 years ago
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