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riadik2000 [5.3K]
3 years ago
13

In the chemical reaction: 2 NaCl (s) + Pb(NO3)2 (aq) ---> 2 NaNO3 (aq) + PbCl2 (s), a student adds 2.5 grams of NaCl(s) to ex

cess lead (II) nitrate solution. What is the theoretical mass, in grams, of the precipitate (solid) formed
Chemistry
1 answer:
lakkis [162]3 years ago
4 0
The amount of the precipitate PbCl2 can be obtained using stoichiometry, assuming the reaction goes into completion given the excess amounts of the lead (II) nitrate solution. First, divide 2.5 g NaCl to its MW of 58.44 g/ mol to obtain the moles of NaCl involved in the reaction. Second, knowing that for every 2 moles of NaCl, there is 1 mole of PbCl2 produced, we divide the moles of NaCl obtained earlier by 2 to get the moles of PbCl2 produced. From the moles of PbCl2, we multiply it to its MW of 278.1 g/ mol. The amount of precipitate is then calculated to be 5.9484 g PbCl2. 
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An electrochemical cell at 25°C is composed of pure copper and pure lead solutions immersed in their respective ionis. For a 0.6
ExtremeBDS [4]

Answer :

(a) The concentration of Pb^{2+} is, 0.0337 M

(b) The concentration of Pb^{2+} is, 6.093\times 10^{32}M

Solution :

<u>(a) As per question, lead is oxidized and copper is reduced.</u>

The oxidation-reduction half cell reaction will be,

Oxidation half reaction:  Pb\rightarrow Pb^{2+}+2e^-

Reduction half reaction:  Cu^{2+}+2e^-\rightarrow Cu

The balanced cell reaction will be,  

Pb(s)+Cu^{2+}(aq)\rightarrow Pb^{2+}(aq)+Cu(s)

Here lead (Pb) undergoes oxidation by loss of electrons, thus act as anode. Copper (Cu) undergoes reduction by gain of electrons and thus act as cathode.

First we have to calculate the standard electrode potential of the cell.

E^o_{[Pb^{2+}/Pb]}=-0.13V

E^o_{[Cu^{2+}/Cu]}=+0.34V

E^o=E^o_{[Cu^{2+}/Cu]}-E^o_{[Pb^{2+}/Pb]}

E^o=0.34V-(-0.13V)=0.47V

Now we have to calculate the concentration of Pb^{2+}.

Using Nernest equation :

E_{cell}=E^o_{cell}-\frac{0.0592}{n}\log \frac{[Pb^{2+}]}{[Cu^{2+}]}

where,

n = number of electrons in oxidation-reduction reaction = 2

E_{cell} = 0.507 V

Now put all the given values in the above equation, we get:

0.507=0.47-\frac{0.0592}{2}\log \frac{[Pb^{2+}]}{(0.6)}

[Pb^{2+}]=0.0337M

Therefore, the concentration of Pb^{2+} is, 0.0337 M

<u>(b) As per question, lead is reduced and copper is oxidized.</u>

The oxidation-reduction half cell reaction will be,

Oxidation half reaction:  Cu\rightarrow Cu^{2+}+2e^-

Reduction half reaction:  Pb^{2+}+2e^-\rightarrow Pb

The balanced cell reaction will be,  

Cu(s)+Pb^{2+}(aq)\rightarrow Cu^{2+}(aq)+Pb(s)

Here Copper (Cu) undergoes oxidation by loss of electrons, thus act as anode. Lead (Pb) undergoes reduction by gain of electrons and thus act as cathode.

First we have to calculate the standard electrode potential of the cell.

E^o_{[Pb^{2+}/Pb]}=-0.13V

E^o_{[Cu^{2+}/Cu]}=+0.34V

E^o=E^o_{[Pb^{2+}/Pb]}-E^o_{[Cu^{2+}/Cu]}

E^o=-0.13V-(0.34V)=-0.47V

Now we have to calculate the concentration of Pb^{2+}.

Using Nernest equation :

E_{cell}=E^o_{cell}-\frac{0.0592}{n}\log \frac{[Cu^{2+}]}{[Pb^{2+}]}

where,

n = number of electrons in oxidation-reduction reaction = 2

E_{cell} = 0.507 V

Now put all the given values in the above equation, we get:

0.507=-0.47-\frac{0.0592}{2}\log \frac{(0.6)}{[Pb^{2+}]}

[Pb^{2+}]=6.093\times 10^{32}M

Therefore, the concentration of Pb^{2+} is, 6.093\times 10^{32}M

6 0
3 years ago
A graduated cylinder is filled 25.0 mL with water and a piece of granite is placed in the cylinder, displacing the level to 37.2
kvv77 [185]

The volume  of the granite piece  in Cm³  is 12.2 cm³

 <u><em>calculation</em></u>

volume of granite = (volume of cylinder after placing granite - volume  of  cylinder  before  placing  granite

 = 37.2 ml - 25.0 ml = 12.2 ml


convert ml  to Cm³

that is 1 ml = 1 cm³

       12.2 ml =  ? cm³

<em>by cross  multiplication</em>

=(12.2 ml x 1 cm³) / 1 ml = 12.2 cm³


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When cells are dividing, it is
DiKsa [7]

Answer:

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Explanation:

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      The DNA is wrapped around the basic protein histone to provide support  the chromosome structure.

    The  wrapping of DNA around the histone proteins helps in the formation of nucleosome which helps in the packing of DNA inside the chromosome.

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If an organism reproduces quickly, its population can ________ faster.
Alexus [3.1K]
If an organism reproduces quickly, its population can evolve faster.
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3 years ago
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What does the symbol (s) represent when it is next to an atom?
AlekseyPX

Answer:

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Explanation:

I hope that helps!! sorry if it dont!

8 0
3 years ago
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