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Andrej [43]
3 years ago
7

When 1.00 g of thiamine hydrochloride (also called vitamin B1 hydrochloride) is dissolved in water, then diluted to 10.00 mL, th

e pH of the resulting solution is 4.50. The formula weight of thiamine hydrochloride is 337.3 g/mol. Calculate Ka.
Chemistry
1 answer:
Semenov [28]3 years ago
4 0

Answer:

Ka= 3.37×10^{-9}

Explanation:

Ka is the measure of an acid's ability to donate H+ ions. A strong acid will have a larger Ka value. Consider the following equation

HA + H2O → H3O+ + A-

where,

HA is acid, which when dissolves in a solution dissociates into hydronium ion and A- ion. Ka will be represented as

Ka = \frac{[H+] [A-]}{[HA]}

Step 1

calculate the number of moles of thiamine hydrochloride

no of moles(n)=g/MM

                    n=1.00/337.3

                   n=2.96×10^{-3}

Step 2

The solution was diluted to 10.00ml

∵ 2.96×10^{-3}/ 0.01 L

  =0.296M

Step 3

Find H+ using the formula

pH= -log [H+}

4.50= -log [H+]

[H]= 10^{-4.50}

[H]=3.16×10^{-5}

Step 4

Substitude the above values in the formula

Ka=\frac{[H+] [A-]}{[HA]}

   =\frac{[0.0000316] [0.000316]}{0.296}

  = 3.37×10^{-9}

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