Match these items.
1 answer:
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Answer:
Part A is just T2 = 58.3 K
Part B ∆U = 10967.6 x C You can work out C
Part C
Part D
Part E
Part F
Explanation:
P = n (RT/V)
V = (nR/P) T
P1V1 = P2V2
P1/T1 = P2/T2
V1/T1 = V2/T2
P = Pressure(atm)
n = Moles
T = Temperature(K)
V = Volume(L)
R = 8.314 Joule or 0.08206 L·atm·mol−1·K−1.
bar = 0.986923 atm
N = 14g/mol
N2 Molar Mass 28g
n = 3.5 mol N2
T1 = 350K
P1 = 1.5 bar = 1.4803845 atm
P2 = 0.25 bar = 0.24673075 atm
Heat Capacity at Constant Volume
Q = nCVΔT
Polyatomic gas: CV = 3R
P = n (RT/V)
0.986923 atm x 1.5 = 3.5 mol x ((0.08206 L atm mol -1 K-1 x 350 K) / V))
V = (nR/P) T
V = ((3.5 mol x 0.08206 L atm mol -1 K-1)/(1.5 x 0.986923 atm) )x 350K
V = (0.28721/1.4803845) x 350
V = 0.194 x 350
V = 67.9036 L
So V1 = 67.9036 L
P1V1 = P2V2
1.4803845 atm x 67.9036 L = 0.24673075 x V2
100.52343693 = 0.24673075 x V2
V2 = P1V1/P2
V2 = 100.52343693/0.24673075
V2 = 407.4216 L
P1/T1 = P2/T2
1.4803845 atm / 350 K = 0.24673075 atm / T2
0.00422967 = 0.24673075 /T2
T2 = 0.24673075/0.00422967
T2 = 58.3 K
∆U= nC ∆T
Polyatomic gas: C = 3R
∆U= nC ∆T
∆U= 28g x C x (350K - 58.3K)
∆U = 28C x 291.7
∆U = 10967.6 x C
Molecules with a plane of symmetry between the chiral centers are achiral and meso. From the given molecules (Picture attached) only (A) compound 1 is meso.
When compounds possess a plane of symmetry between the chiral centers they are called achiral or meso compounds. Among the given compounds (A) compound 1 have a plane of symmetry. So we can say compound one is a meso or achiral compound. Compounds two, three, and four have no plane of symmetry, as you can see in the structures attached. So all other compounds (compound 2, compound 3, and compound 4) except compound one are not meso or achiral.
You can also learn about meso compounds from the following question:
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