Answer:
The major limitations of Newlands' law of octaves were : (i) It was applicable to only lighter elements having atomic masses upto 40 u, i.e., upto calcium. After calcium, the first and the eighth element did not have similar properties
"Increase Pressure " is the right answer. if you need help , let me know
Answer:
a) ΔGº= -49,9 KJ/mol = - 50 KJ/mol
b) The reaction goes to the right to formation of products
c) ΔG= 84,42 KJ/mol. The direction is to reactive, to the left
Explanation:
a) ΔGº= - RTLnKf
You need to convert Cº to K. 25ºC=298K
Then, ΔGº= - 3,814 J/molK * 298K* Ln(5.6 *10^8)= - 49906 J/mol = -49,9 KJ/mol = - 50 KJ/mol
b) The ΔGº < 0, that means the direct reaction is spontaneous when te reactive and products are in standard state. In other words the reaction goes to the right, to formation of products
c) The general ecuation for chemical reaction is aA + bB → cD + dD. Thus
ΔG=ΔGº + RTLn (([C]^c*[D]^d)/[A]^a*[B]^b)
In this case,
ΔG=ΔGº + RTLn ([Ni(NH3)62+] / [Ni2+]*[NH3]^6 )= 84417 J/mol =84,42 KJ/mol
ΔG >0 means the reaction isn't spontaneous in the direction of the products. Therefore the direction is to reactive, to the left
