This is what I got. Hope it helps :)
It would contain 0.105M moles of NaOH in each liter of solution
Here we have to get the
of the reaction at 520 K temperature.
The
of the reaction is 1.705 atm
We know the relation between
and
is
, where
= The equilibrium constant of the reaction in terms of partial pressure,
= The equilibrium constant of the reaction in terms of concentration and N = number of moles of gaseous products - Number of moles of gaseous reactants.
Now in this reaction, PCl₃ + Cl₂ ⇄ PCl₅
Thus number of moles of gaseous product is 1, and number of moles of gaseous reactants are 2. Thus N = |1 - 2| = 1 mole
The given value of
is 4.0×10⁻²
The molar gas constant, R = 0.082 L. Atm. mol⁻¹. K⁻¹ and temperature, T = 520 K.
On plugging the values in the equation we get,

Or,
= 1.705 atm
Thus, the
of the reaction is 1.705 atm
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Answer:
- <u>2.59 × 10⁻⁷ m = 259 nm</u>
Explanation:
You need to calculate the wavelength of a photon with an energy equal to 463 kJ/mol, which is the energy to break an oxygen-hydrogen atom.
The energy of a photon and its wavelength are related by the Planck - Einstein equation:
Where:
- h = Planck constant (6.626 × 10⁻³⁴ J . s) and
- ν = frequency of the photon.
And:
Where:
- c = speed of light (3.00 × 10⁸ m/s in vacuum)
- λ = wavelength of the photon
Thus, you can derive:
Solve for λ:
Before substituting the values, convert the energy, 463 kJ/ mol, to J/bond
- 463 kJ/ mol × 1,000 J/kJ × 1 mol / 6.022 × 10 ²³ atom × 1 bond / atom
= 7.69×10²³ J / bond
Substitute the values and use the energy of one bond:
- λ = 6.626 × 10⁻³⁴ J . s × 3.00 × 10⁸ m/s / 7.69×10²³ J = 2.59 × 10⁻⁷ m
The wavelength of light is usually shown in nanometers:
- 2.59 × 10⁻⁷ m × 10⁹ nm / m = 259 nm ← answer