The empirical formula of the following compounds 0.903 g of phosphorus combined with 6.99 g of bromine.
<h3>What is empirical formula?</h3>
The simplest whole number ratio of atoms in a compound is the empirical formula of a chemical compound in chemistry. Sulfur monoxide's empirical formula, SO, and disulfur dioxide's empirical formula, S2O2, are two straightforward examples of this idea. As a result, both the sulfur and oxygen compounds sulfur monoxide and disulfur dioxide have the same empirical formula.
<h3>
How to find the empirical formula?</h3>
Convert the given masses of phosphorus and bromine into moles by multiplying the reciprocal of their molar masses. The molar masses of phosphorus and bromine are 30.97 and 79.90 g/mol, respectively.
Moles phosphorus = 0.903 g phosphorus
= 0.0293 mol
Moles bromine 6.99 g bromine
=0.0875 mol
The preliminary formula for compound is P0.0293Bro.0875. Divide all the subscripts by the subscript with the smallest value which is 0.0293. The empirical formula is P1.00Br2.99 ≈ P₁Br3 or PBr3
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Answer:
The correct answer is entropy change of the surrounding plus the entropy change of the system must be positive.
Explanation:
The term entropy is a state function.Entropy can be defined as the disorder or randomness of the molecules in a system.
A spontaneous reaction is a type of reaction which deals with the release of free energy.The change of free energy in case of spontaneous reaction is always negative.
According to the second law of thermodynamics a spontaneous reaction will occur in a system if the total entropy of both system and surrounding increases during the reaction.
<h3><u>Answer;</u></h3>
<em>-49 °C</em>
<h3><u>Explanation and solution;</u></h3>
- Considering the fact that, the specific heat capacity of aluminum is 0.903 J/g x C, and the heat of vaporization of water at 25 C is 44.0 KJ/mol.
Moles water = 0.48 g / 18.02 g/mol
=0.0266 moles
<em>Heat lost by water</em> = 0.0266 mol x 44.0 kJ/mol
=1.17 kJ => 1170 J
<em>But heat lost =heat gained</em>
<em>Therefore;</em> Heat gained by aluminium = 1170 J
1170 = 55 x 0.903 ( T - 25) = 49.7 T - 1242
1170 + 1242 = 49.7 T
T = 48.5 °C ( 49 °C <em>at two significant figures)</em>
<em>Hence</em>, final temperature = 49 °C
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