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3 years ago

Whats the molar volume (of a solution)?

Chemistry

1 answer:

il63 [147K]3 years ago

7 0

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Answer:

Molarity can be used to calculate the volume of solvent or the amount of solute. The relationship between two solutions with the same amount of moles of solute can be represented by the formula c1V1 = c2V2, where c is concentration and V is volume.

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Consider the following reaction: A(g)⇌2B(g). Find the equilibrium partial pressures of A and B for each of the following differe

Illusion [34]

Answer:

a. Kp=1.4

$P_{A}=0.2215 atm$

$P_{B}=0.556 atm$

b.Kp=2.0 * 10^-4

$P_{A}=0.495atm$

$P_{B}=0.00995 atm$

c.Kp=2.0 * 10^5

$P_{A}=5*10^{-6}atm$

$P_{B}=0.9999 atm$

Explanation:

For the reaction

A(g)⇌2B(g)

Kp is defined as:

$Kp=\frac{(P_{B})^{2}}{P_{A}}$

The conditions in the system are:

A B

initial 0 1 atm

equilibrium x 1atm-2x

At the beginning, we don’t have any A in the system, so B starts to react to produce A until the system reaches the equilibrium producing x amount of A. From the stoichiometric relationship in the reaction we get that to produce x amount of A we need to 2x amount of B so in the equilibrium we will have 1 atm – 2x of B, as it is showed in the table.

Replacing these values in the expression for Kp we get:

$Kp=\frac{(1-2x)^{2}}{x}$

Working with this equation:

$x*Kp=(1-2x)^{2} - -> x*Kp=4x^{2}-4x+1- - >4x^{2}-(4+Kp)*x+1=0$

This last expression is quadratic expression with a=4, b=-(4+Kp) and c=1

The general expression to solve these kinds of equations is:

$x=\frac{-b(+-)*\sqrt{(b^{2}-4ac)}}{2a}$ (equation 1)

We just take the positive values from the solution since negative partial pressures don´t make physical sense.

Kp = 1.4

$x_{1}=\frac{(1.4+4)+\sqrt{(-(1.4+4)^{2}-4*4*1)}}{2*4}=1.128$

$x_{1}=\frac{(1.4+4)-\sqrt{(-(1.4+4)^{2}-4*4*1)}}{2*4}=0.2215$

With x1 we get a partial pressure of:

$P_{A}=1.128 atm$

$P_{B}=1-2*1.128 = -1.256 atm$

Since negative partial pressure don´t make physical sense x1 is not the solution for the system.

With x2 we get:

$P_{A}=0.2215 atm$

$P_{B}=1-2*0.2215 = 0.556 atm$

These partial pressures make sense so x2 is the solution for the equation.

We follow the same analysis for the other values of Kp.

Kp=2*10^-4

X1=0.505

X2=0.495

With x1

$P_{A}=0.505atm$

$P_{B}=1-2*0.505 = -0.01005 atm$

Not sense.

With x2

$P_{A}=0.495atm$

$P_{B}=1-2*0.495 = 0.00995 atm$

X2 is the solution for this equation.

Kp=2*10^5

X1=50001

$X2=5*10^{-6}$

With x1

$P_{A}=50001atm$

$P_{B}=1-2*50001=-100001atm$

Not sense.

With x2

$P_{A}= 5*10^{-6}atm$

$P_{B}=1-2*5*10^{-6}= 0.9999 atm$

X2 is the solution for this equation.

8 0

3 years ago

If a sample of oxygen occupies a volume of 2.15 L at a pressure of 58.0 kPa and a temperature of 25°C, what volume would this sa

Anna35 [415]

The answer is A) 1.13 L

8 0

3 years ago

Base changes phenolphthalein to pink it is true or false

galben [10]

Answer:

It’s false

Explanation:

it could be true if the question mentioned alkaline solution

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2 years ago

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If there are 40 mol of NBr3 and 48 mol of NaOH, what is the excess reactant?

Nata [24]

Answer:

The correct answer is option B.

Explanation:

$3NaOH+2NBr_3\rightarrow 3HOBr+3NaBr+N_2$

Moles of $NBr_3$ = 40 mol

Moles of NaOH = 48 mol

According to reaction, 3 moles of NaOH reacts with 2 moles $NBr_3$

Then ,48 moles of NaOH will reacts with:

$\frac{2}{3}\times 48 mol=32 mol$ of $NBr_3$

Then ,40 moles of $NaBr_3$ will reacts with:

$\frac{3}{2}\times 40 mol=60 mol$ of NaOH

As we can see that 48 moles of sodium will completey react with 32 moles of nitrogen tribromide.

Moles left after reaction = 40 mol - 32 mol = 8 mol

Hence, the $NBr_3$ is an excessive reagent.

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3 years ago

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How does a balanced chemical equation verify the law of conservation of matter?

murzikaleks [220]

Answer:

$\color {pink}\boxed{\colorbox{black} { QUESTION♡}}$

How does a balanced chemical equation verify the law of conservation of matter?

$\color {pink}\boxed{\colorbox{white} {✦Answer✦}}$

According to the Law conservation of matter

Mass can neither be created nor destroyed in a chemical reaction. That is, the total mass of the elements present in the products of a chemical reaction has to be equal to the total mass of the elements present in the reactants. In other words, the number of atoms of each element remains the same, before and after a chemical reaction. Hence, we need to balance the skeletal chemical equation.

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2 years ago