Write the Henderson-Hasselbalch equation for a solution of formic acid. Calculate the quotient [HCO2]/[HCO2H] at (a) pH 3.000; (
1 answer:
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The question is incomplete, complete question is :
The frequency factors for these two reactions are very close to each other in value. Assuming that they are the same, compute the ratio of the reaction rate constants for these two reactions at 25°C.
Activation energy of the reaction 1 , = 14.0 kJ/mol
Activation energy of the reaction 2, = 11.9 kJ/mol
Answer:
0.4284 is the ratio of the rate constants.
Explanation:
According to the Arrhenius equation,
The expression used with catalyst and without catalyst is,
where,
= rate constant reaction -1
= rate constant reaction -2
Activation energy of the reaction 1 , = 14.0 kJ/mol = 14,000 J
Activation energy of the reaction 2, = 11.9 kJ/mol = 11,900 J
R = gas constant = 8.314 J/ mol K
T = temperature =
Now put all the given values in this formula, we get
0.4284 is the ratio of the rate constants.
Answer:
<u>It increases by a factor of four</u>
Explanation:
Boyle's Law : At constant temperature , the volume of fixed mass of a gas is inversely proportional to its pressure.
pV = K.......(1)
pV = constant
Charles law : The volume of the gas is directly proportional to temperature at constant pressure.
V = KT
or V/T = K = constant ....(2)
Applying equation (1) and (2)
According to question ,
T2 = 4 (T1)
V2 = V1
Put the value of T2 and V2 , The P2 can be calculated,
V1 and V1 cancel each other
T1 and T1 cancel each other
We get,
or
P2 = 4 P1
So pressure increased by the factor of four