Only the amount of gas is held constant.
The gas is confined in 3.0 L container ( rigid container) ⇒ the volume remains constant when the temperature is increased from from 27oC to 77oC and therefore V1=V2 .
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The correct option is D.
When dissolving a substance in a solvent, stirring the solution will increased the rate at which the substance dissolved. This is because, when one stirs a solution, it exposes more surface area of the solute to the solvent, thus, increasing the interaction between the solute and the solvent. The higher the quantity of the solute that is exposed to the solvent, the higher the rate of dissolution of the solute.