The Nernst equation allows us to predict the cell potential for voltaic cells under conditions other than the standard conditions of 1M, 1 atm, 25°C. The effects of different temperatures and concentrations may be tracked in terms of the Gibbs energy change ΔG. This free energy change depends upon the temperature & concentrations according to ΔG = ΔG° + RTInQ where ΔG° is the free energy change under conditions and Q is the thermodynamic reaction quotient. The free energy change is related to the cell potential Ecell by ΔG= nFEcell
so for non-standard conditions
-nFEcell = -nFE°cell + RT InQ
or
Ecell = E°cell - RT/nF (InQ)
which is called Nernst equation.
If the reaction is represented by:
PCl₃ + Cl₂ <-> PCl₅ (exothermic)
the mole fraction of chlorine in the equilibrium mixture will change according to the following:
Decrease the volume: decrease
Increase the temperature: increase
Increase the volume: increase
Decrease the temperature: decrease
You can not see between opaque materials because light cannot pass through them.
Answer:
When the volume of product increases.
When the weight of the product decreases.
Option (a) and (d) are correct.
Explanation:
The overall density of the product can be decreased:
a. Increase the volume of the product (and keep the material same)
d. Decrease the weight of the product ( and keep the same material ).
Density is calculated as the ratio of mass to the volume.
Density is inversely related to volume and directly related to mass.
So, when the mass of the product is increased then the density will increase keeping the material same. Density will also increase when the volume of the product decreased.
C. NaOH ammmonia is also an base but not as strong as NaOH