Answer: Mg is the excess reactant for the forward reaction.
Explanation: It is a stoichiometry problem and solved with the help of given grams and using balanced equation. Grams of both the reactants are converted to moles and divided by their coefficients. The excess reactant is the one for which we get the highest number on doing above steps.
The balanced equation is:

Molar mass of silicon tetra chloride is 169.9 gram per mol and the molar mass of Mg is 24.3 gram per mol.

= 

= 2.67 mol Mg
From balanced equation, the coefficient of silicon tetra chloride is 1 and that of Mg is 2. So, we will divide the moles of silicon tetra chloride by 1 and that of Mg by 2 and see which one gives highest number.
For silicon tetra chloride,
= 0.317
and for Mg,
= 1.34
The highest number is for Mg and so the excess reactant for the forward reaction is Mg.
Answer:
Boiling water is an example of a physical change and not a chemical change because the water vapor still has the same molecular structure as liquid water (H2O).
Explanation:
Answer is: the absolute pressure of the air in the balloon is 1.015 atm (102.84 kPa).
n = 0.250 mol; amount of substance.
V = 6.23 L; volume of the balloon.
T = 35°C = 308.15 K; temperature.
R = 0.08206 L·atm/mol·K, universal gas constant.
Ideal gas law: p·V = n·R·T.
p = n·R·T / V.
p = 0.250 mol · 0.08206 L·atm/mol·K · 308.15 K / 6.23 L.
p = 1.015 atm; presure of the air.