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hichkok12 [17]
3 years ago
14

Which member of each pair is the stronger base? part a ethylamine or aniline ethylamine or aniline ethylamine aniline request an

swer part b ethylamine or ethoxide ion ethylamine or ethoxide ion ethylamine ethoxide ion?

Chemistry
1 answer:
Vladimir79 [104]3 years ago
5 0
Lowery-Bronsted theory is applied here. Acc. to this theory Base accepts protons and Acids donate proton.

Part 1: 
Aniline is less basic than ethylamine because the lone pair on nitrogen (which accepts proton) is not localized. It resonates throughout the conjugated system of phenyl ring. Hence due to unavailability of electrons for accepting proton it is less basic compare to ethylamine. In ethyl amine the lone pair of electron is localized and available to abstract proton.

Part 2:
In this case the alkyl groups attached to -NH₂ (in ethylamine) and -O⁻ (in ethoxide are same (i.e. CH₃-CH₂-). Ethoxide is more basic than ethylamine because ethoxide is a conjugate base of ethanol (pKa value of ethanol = 15.9 very weak acid) and the conjugate base of weak acid is always a strong base. Secondly, the oxygen atom more Electronegative than Nitrogen atom can attract more electron cloud from alkyl group as compared to Nitrogen in ethylamine. Hence, oxygen in ethoxide attains greater electron cloud than the nitrogen in ethylamine. Therefore, it is more basic than ethylamine.

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The number of mole of ammonium ion, NH₄⁺ in the solution is 0.175 mole

We'll begin by calculating the number of mole of NH₄NO₃ in the solution. This can be obtained as follow:

Volume = 125 mL = 125 / 1000 = 0.125 L

Molarity = 1.40 M

<h3>Mole of NH₄NO₃ =? </h3>

Mole = Molarity x Volume

Mole of NH₄NO₃ = 1.40 × 0.125

<h3>Mole of NH₄NO₃ = 0.175 mole</h3>

Finally, we shall determine the number of mole of ammonium ion, NH₄⁺ in the solution. This can be obtained as follow:

NH₄NO₃(aq) —> NH₄⁺(aq) + NO₃¯(aq)

From the balanced equation above,

1 mole of NH₄NO₃ contains 1 mole of NH₄⁺

Therefore,

0.175 mole of NH₄NO₃ will also contain 0.175 mole of NH₄⁺

Thus, the number of mole of ammonium ion, NH₄⁺ in the solution is 0.175 mole

Learn more: brainly.com/question/25469095

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