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3 years ago

Physical and chemical change

2 answers:

5 0

physical change in a substance doesn't change what the substance is. In a chemical change where there is a chemical reaction, a new substance is formed and energy is either given off or absorbed. For example, if a piece of paper is cut up into small pieces it still is paper.

lina2011 [118]3 years ago

5 0

Chemical change: a change that occurs when one substance combines with another substance to make a new substance

Physical change: a change to any physical property of a substance

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The unit cell for cr2o3 has hexagonal symmetry with lattice parameters a = 0.4961 nm and c = 1.360 nm. If the density of this ma

IRINA_888 [86]

To calculate the packing factor, first calculate the area and volume of unit cell.

Area is calculated as:

$A=6R^{2}\sqrt{3}$

Here, R is radius and is related to a as follows:

$R=\frac{a}{2}$

Putting the value in expression for area,

$A=6(\frac{a}{2})^{2}\sqrt{3}=1.5a^{2}\sqrt{3}$

The value of a is 0.4961 nm

Since, $1 nm=10^{-7}cm$

Thus, $0.4961 nm=4.961\times 10^{-8} cm$

Putting the value,

$Area=1.5(4.961\times 10^{-8}cm)^{2}\sqrt{3}=6.39\times 10^{-15}cm^{2}$

Now, volume can be calculated as follows:

$V=Area\times c$

The value of c is 1.360 nm or $1.360\times 10^{-7} cm$

Putting the value,

$V=(6.39\times 10^{-15}cm^{2})\times (1.360\times 10^{-7} cm)=8.7\times 10^{-22}cm^{3}$

now, number of atom in unit cell can be calculated by using the following formula:

$n=\frac{\rho N_{A}V_{c}}{A}$

Here, A is atomic mass of $Cr_{2}O_{3}$ is 151.99 g/mol.

Putting all the values,

$n=\frac{(5.22 g/cm^{3})(6.023\times 10^{23} mol^{-1})(8.7\times 10^{-22}cm^{3})}{(151.99 g/mol)}\approx 18$

Thus, there will be 18 $Cr_{2}O_{3}$ units in 1 unit cell.

Since, there are 2 Cr atoms and 3 oxygen atoms thus, units of chromium and oxygen will be 2×18=36 and 3×18=54 respectively.

The atomic radii of $Cr^{3+}$ and $O^{2-}$ is 62 pm and 140 pm respectively.

Converting them into cm:

$1 pm=10^{-10}cm$

Thus,

$r_{Cr^{3+}}=6.2\times 10^{-9}cm$

and,

$r_{O^{2-}}=1.4\times 10^{-8}cm$

Volume of sphere will be sum of volume of total number of cations and anions thus,

$V_{S}=V_{Cr^{3+}}+V_{O^{2-}}$

Since, volume of sphere is $V=\frac{4}{3}\pi r^{3}$ ,

$V_{S}=36\left ( \frac{4}{3}\pi (r_{Cr^{3+})^{3}} \right )+54\left ( \frac{4}{3}\pi (r_{O^{2-})^{3}} \right )$

Putting the values,

$V_{S}=36\left ( \frac{4}{3}(3.14) (6.2\times 10^{-9} cm)^{3}} \right )+54\left ( \frac{4}{3}(3.14) (1.4\times 10^{-8} cm)^{3}} \right )=6.6\times 10^{-22}\times 10^{-8}cm^{3}$

The atomic packing factor is ratio of volume of sphere and volume of crystal, thus,

$packing factor=\frac{V_{S}}{V_{C}}=\frac{6.6\times 10^{-22}cm^{3}}{8.7\times 10^{-22}cm^{3}}=0.758$

Thus, atomic packing factor is 0.758.

6 0

3 years ago

Read 2 more answers

stbank, Question 075 Get help answering Molecular Drawing questions. Compound A, C6H12 reacts with HBr/ROOR to give compound B,

Law Incorporation [45]

Answer:

Explanation:

In this case we want to know the structures of A (C6H12), B (C6H13Br) and C (C6H14).

A and C reacts with two differents reagents and conditions, however both of them gives the same product.

Let's analyze each reaction.

First, C6H12 has the general formula of an alkene or cycloalkane. However, when we look at the reagents, which are HBr in ROOR, and the final product, we can see that this is an adition reaction where the H and Br were added to a molecule, therefore we can conclude that the initial reactant is an alkene. Now, what happens next? A is reacting with HBr. In general terms when we have an adition of a molecule to a reactant like HBr (Adding electrophyle and nucleophyle) this kind of reactions follows the markonikov's rule that states that the hydrogen will go to the carbon with more hydrogens, and the nucleophyle will go to the carbon with less hydrogen (Atom that can be stabilized with charge). But in this case, we have something else and is the use of the ROOR, this is a peroxide so, instead of follow the markonikov rule, it will do the opposite, the hydrogen to the more substituted carbon and the bromine to the carbon with more hydrogens. This is called the antimarkonikov rule. Picture attached show the possible structure for A. The alkene would have to be the 1-hexene.

Now in the second case we have C, reacting with bromine in light to give also B. C has the formula C6H14 which is the formula for an alkane and once again we are having an adition reaction. In this case, conditions are given to do an adition reaction in an alkane. bromine in presence of light promoves the adition of the bromine to the molecule of alkane. In this case it can go to the carbon with more hydrogen or less hydrogens, but it will prefer the carbon with more hydrogens. In this case would be the terminal hydrogens of the molecules. In this case, it will form product B again. the alkane here would be the hexane. See picture for structures.

8 0

4 years ago

Gerald's science teacher mixed liquid X and liquid Y, both at room-temperature, in a large beaker. two beakers of clear solution

Pachacha [2.7K]

Answer:

the answer is C

Explanation:

7 0

3 years ago

Read 2 more answers

The atomic number of lead is 82. Its mass number is 207?.how many protons neutrons and electros does the atom of lead contain

kupik [55]

Lead have:

82 electrons

82 protons

125 neutrons

Explanation:

The number of electrons and protons are given by the atomic number of the element.

Lead have 82 electrons and 82 protons.

The number of neutrons are given by the difference between the mass number and atomic number.

For lead number of neutrons = 207 - 82 = 125.

Learn more about:

particles in the atom

brainly.com/question/439508

#learnwithBrainly

4 0

3 years ago

Air, with an initial absolute humidity of 0.016 kg water per kg dry air, is to be dehumidified for a drying process by an air co

amid [387]

Answer:

(a) The proportion of dry air bypassing the unit is 14.3%.

(b) The mass of water removed is 1.2 kg per 100 kg of dry air.

Explanation:

We can express the proportion of air that goes trough the air conditioning unit as $p_{d}$ and the proportion of air that is by-passed as $p_{bp}$ , being $p_{d}+p_{bp}=1$ .

The amount of water that goes into the drier inlet has to be 0.004 kg/kg, and can be expressed as:

$0.004 = 0.016*p_{bp}+ 0.002*p_{d}$

Replacing the first equation in the second one we have

$0.004 = 0.016*(1-p_{d})+ 0.002*p_{d}=0.016-0.016*p_{d}+0.002*p_{d}\\0.004 - 0.016 = (-0.016+0.002)*p_{d}\\-0.012 = -0.014*p_{d}\\p_{d}=\frac{-0.012}{-0.014}=0.857\\\\p_{bp}=1-p_{d}=1-0.857=0.143$

(b) Of every kg of dry air feed, 85.7% goes in to the air conditioning unit.

It takes (0.016-0.002)=0.014 kg water per kg dry air feeded.

The water removed of every 100 kg of dry air is

$100 kgDA*0.857*0.014 kgW/kgDA= 1.1998 \approx 1.2 kgW$

It can also be calculated as the difference in humiditiy between the inlet and the outlet: (0.016-0.004=0.012 kgW/kDA) and multypling by the total amount of feed (100 kgDA).

100 * 0.012 = 1.2 kgW

7 0

4 years ago