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VladimirAG [237]
3 years ago
6

When a aqueous solution of a certain acid is prepared, the acid is dissociated. Calculate the acid dissociation constant of the

acid. Round your answer to significant digits.
Chemistry
1 answer:
stepan [7]3 years ago
6 0
<h2>K_a = \dfrac{[H^{+}] [A^{-}]}{[HA]}</h2>

Explanation:

  • When an aqueous solution of a certain acid is prepared it is dissociated is as follows-

        {\displaystyle {\ce {HA  ⇄  {H^+}+{A^{-}}}  }}

Here HA is a protonic acid such as acetic acid, CH_3COOH

  • The double arrow signifies that it is an equilibrium process, which means the dissociation and recombination of the acid occur simultaneously.
  • The acid dissociation constant can be given by -

        K_a = \dfrac{[H^{+}] [A^{-}]}{[HA]}

  • The reaction is can also be represented by Bronsted and lowry -

         \\{\displaystyle {\ce {{HA}+ H_2O} ⇄  [H_3O^+] [A^-]

  • Then the dissociation constant will be

        K_a = \dfrac{[H_3O^{+}] [A^{-}]}{[HA]}

Here, K_a is the dissociation constant of an acid.

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Calculate the standard reaction Gibbs free energy for the following cell reactions: (a) 2 Ce41(aq) 1 3 I2(aq) S 2 Ce31(aq) 1 I32
Law Incorporation [45]

<u>Answer:</u>

<u>For a:</u> The standard Gibbs free energy of the reaction is -347.4 kJ

<u>For b:</u> The standard Gibbs free energy of the reaction is 746.91 kJ

<u>Explanation:</u>

Relationship between standard Gibbs free energy and standard electrode potential follows:

\Delta G^o=-nFE^o_{cell}           ............(1)

  • <u>For a:</u>

The given chemical equation follows:

2Ce^{4+}(aq.)+3I^{-}(aq.)\rightarrow 2Ce^{3+}(aq.)+I_3^-(aq.)

<u>Oxidation half reaction:</u>   Ce^{4+}(aq.)\rightarrow Ce^{3+}(aq.)+e^-       ( × 2)

<u>Reduction half reaction:</u>   3I^_(aq.)+2e^-\rightarrow I_3^-(aq.)

We are given:

n=2\\E^o_{cell}=+1.08V\\F=96500

Putting values in equation 1, we get:

\Delta G^o=-2\times 96500\times (+1.80)=-347,400J=-347.4kJ

Hence, the standard Gibbs free energy of the reaction is -347.4 kJ

  • <u>For b:</u>

The given chemical equation follows:

6Fe^{3+}(aq.)+2Cr^{3+}+7H_2O(l)(aq.)\rightarrow 6Fe^{2+}(aq.)+Cr_2O_7^{2-}(aq.)+14H^+(aq.)

<u>Oxidation half reaction:</u>   Fe^{3+}(aq.)\rightarrow Fe^{2+}(aq.)+e^-       ( × 6)

<u>Reduction half reaction:</u>   2Cr^{2+}(aq.)+7H_2O(l)+6e^-\rightarrow Cr_2O_7^{2-}(aq.)+14H^+(aq.)

We are given:

n=6\\E^o_{cell}=-1.29V\\F=96500

Putting values in equation 1, we get:

\Delta G^o=-6\times 96500\times (-1.29)=746,910J=746.91kJ

Hence, the standard Gibbs free energy of the reaction is 746.91 kJ

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the element chlorine is represented by the symbol Cl

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2 years ago
Can someone help me identify the elements please, i rlly need help
rewona [7]

Answer:

1 : any of more than 100 substances that cannot by ordinary chemical means be separated into different substances Gold and carbon are elements. 2 : one of the parts of which something is made up There is an element of risk in surfing. 3 : the simplest principles of a subject of study the elements of arithmetic.

Explanation:

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aivan3 [116]

Answer:

A. = 143

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Explanation:

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