Answer:
ΔH = 
Explanation:
In a calorimeter, when there is a complete combustion within the calorimeter, the heat given off in the combustion is used to raise the thermal energy of the water and the calorimeter.
The heat transfer is represented by
=
where
= the internal heat gained by the whole calorimeter mass system, which is the water, as well as the calorimeter itself.
= the heat of combustion
Also, we know that the total heat change of the any system is
ΔH = ΔQ + ΔW
where
ΔH = the total heat absorbed by the system
ΔQ = the internal heat absorbed by the system which in this case is
ΔW = work done on the system due to a change in volume. Since the volume of the calorimeter system does not change, then ΔW = 0
substituting into the heat change equation
ΔH = + 0
==> ΔH =
Answer:
Decreasing the temperature will shift the equilibrium leftwards towards reactants.
Explanation:
Hello!
In this case, since the reaction between chromate anions and hydrogen ions yields dichromate anions, water and heat, we can infer this is an exothermic reaction by which heat is released (remember in endothermic reactions heat is absorbed as a reactant), it means that considering the LeChatelier’s which states that increasing the temperature of an exothermic reaction shifts the equilibrium leftwards since heat is a product, otherwise (decreasing the temperature) the equilibrium will be shifted rightwards.
Therefore, decreasing the temperature is the perturbation that will shift the equilibrium leftwards towards the reactants.
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2 ICl + H2 ----> I2 + 2 HCl
as given that rate is first order with respect to ICl and second order with respect to H2
The rate law will be
Rate = K [ICl] [ H2]^2
b) Given that K = 2.01 M^-2 s^-1
Concentrations are
[ICl] = 0.273 m and [H2] = 0.217 m
Therefore rate = 2.01 X (0.273)(0.217)^2 = 0.0258 M / s
