Answer:
The pH is equal to 4.41
Explanation:
Since HClO is a weak acid, its dissociation in aqueous medium is:
HClO ⇄ ClO- + H+
start: 0.05 0 0
change -x +x +x
balance 0.05-x x x
As it is a weak acid it dissociates very little, in its ClO- and H + ions, so the change is negative, where x is a degree of dissociation.
the acidity constant when equilibrium is reached is equal to:
![Ka=\frac{[ClO-]*[H+]}{[HClO]}=\frac{x*x}{0.05-x}=3x10^{-8}](https://tex.z-dn.net/?f=Ka%3D%5Cfrac%7B%5BClO-%5D%2A%5BH%2B%5D%7D%7B%5BHClO%5D%7D%3D%5Cfrac%7Bx%2Ax%7D%7B0.05-x%7D%3D3x10%5E%7B-8%7D)
The 0.05-x fraction can be approximated to 0.05, because the ionized fraction (x) is very small, therefore we have:

clearing the x and calculating its value we have:
![x=3.87x10^{-5}=[H+]=[ClO-]](https://tex.z-dn.net/?f=x%3D3.87x10%5E%7B-5%7D%3D%5BH%2B%5D%3D%5BClO-%5D)
the pH can be calculated by:
![pH=-log[H+]=-log[3.87x10^{-5}]=4.41](https://tex.z-dn.net/?f=pH%3D-log%5BH%2B%5D%3D-log%5B3.87x10%5E%7B-5%7D%5D%3D4.41)
Answer:
74.4 ml
Explanation:
C₆H₈O₇(aq) + 3NaHCO₃(s) => Na₃C₆H₅O₃(aq + 3CO₂(g) + 3H₂O(l)
Given 15g = 15g/84g/mol = 0.1786mole Sodium Bicarbonate
From equation stoichiometry 3moles NaHCO₃ is needed for each mole citric acid or, moles of citric acid needed is 1/3 of moles sodium bicarbonate used.
Therefore, for complete reaction of 0.1786 mole NaHCO₃ one would need 1/3 of 0.1786 mole citric acid or 0.0595 mole H-citrate.
The question is now what volume of 0.8M H-citrate solution would contain 0.0595mole of the H-citrate? This can be determined from the equation defining molarity. That is => Molarity = moles solute / Liters of solution
=> Volume (Liters) = moles citric acid / Molarity of citric acid solution
=> Volume needed in liters = 0.0.0595 mole/0.80M = 0.0744 Liters or 74.4 ml
<h2>Hello!</h2>
The answer is: 4.77atm
<h2>Why?</h2>
Since there's a fixed volume, we can use the the Gay-Lussac's Law which stablish a relation between the pressure and the temperature:

<em>P</em> is the volume of the gas
<em>t</em> is the temperature of the gas
<em>k </em>is the proportionality constant
We also have the following equation:

Where:

We are asked to find the pressure in atm, so we must convert 483.73kPa to atm:

Then,

Have a nice day!