Question

Use enthalpies of formation given in appendix c to calculate δh for the reaction br2(g)→2br(g), and use this value to estimate the bond enthalpy d(br−br).

Answer 1

Given reaction represents dissociation of bromine gas to form bromine atoms

Br2(g) ↔ 2Br(g)

The enthalpy of the above reaction is given as:

ΔH = ∑n(products)Δ$H^{0}f(products)$ - ∑n(reactants)Δ$H^{0}f(reactants)$

where n = number of moles

Δ$H^{0}f$= enthalpy of formation

ΔH = [2*ΔH(Br(g)) - ΔH(Br2(g))] = 2*111.9 - 30.9 = 192.9 kJ/mol

Thus, enthalpy of dissociation is the bond energy of Br-Br = 192.9 kJ/mol