Answer:
Explanation:
We must use the Nernst equation
1. Write the equation for the cell reaction
If you want the reduction potential, the pH 5.65 solution is the cathode, and the cell reaction is
<u> E°/V</u>
Anode: H₂(1 bar) ⇌ 2H⁺(1 mol·L⁻¹) + 2e⁻; 0
Cathode: <u>2H⁺(pH 5.65) + 2e⁻ ⇌ H₂(1 bar)</u>; <u> 0 </u>
Overall: 2H⁺ (pH 5.65) ⇌ 2H⁺(1 mol·L⁻¹); 0
Step 2. Calculate E°
(a) Data
E° = 0
R = 8.314 J·K⁻¹mol⁻¹
T = 25 °C
n = 2
F = 96 485 C/mol
pH = 5.65
Calculations:
T = 25 + 273.15 = 298.15 K
![\text{H}^{+} = 10^{\text{-pH}} = 2.24 \times 10^{-5}\text{ mol/\L}\\\\Q = \dfrac{\text{[H}^{+}]_{\text{prod}}^{2}}{\text{[H}^{+}]_{\text{react}}^{2}} = \dfrac{(1.00)^{2}}{(2.24 \times 10^{-5})^{2}} =2.00 \times 10^{9}\\\\\\E = 0 - \left (\dfrac{8.314 \times 298.15 }{2 \times 96485}\right ) \ln{2.00 \times 10^{9}}\\\\= -0.01285 \times 21.41 = \textbf{-0.275 V}\\\text{The cell potential for the cell as written is }\boxed{\textbf{-0.275 V}}](https://tex.z-dn.net/?f=%5Ctext%7BH%7D%5E%7B%2B%7D%20%3D%2010%5E%7B%5Ctext%7B-pH%7D%7D%20%3D%202.24%20%5Ctimes%2010%5E%7B-5%7D%5Ctext%7B%20mol%2F%5CL%7D%5C%5C%5C%5CQ%20%3D%20%5Cdfrac%7B%5Ctext%7B%5BH%7D%5E%7B%2B%7D%5D_%7B%5Ctext%7Bprod%7D%7D%5E%7B2%7D%7D%7B%5Ctext%7B%5BH%7D%5E%7B%2B%7D%5D_%7B%5Ctext%7Breact%7D%7D%5E%7B2%7D%7D%20%3D%20%5Cdfrac%7B%281.00%29%5E%7B2%7D%7D%7B%282.24%20%5Ctimes%2010%5E%7B-5%7D%29%5E%7B2%7D%7D%20%3D2.00%20%5Ctimes%2010%5E%7B9%7D%5C%5C%5C%5C%5C%5CE%20%3D%200%20-%20%5Cleft%20%28%5Cdfrac%7B8.314%20%5Ctimes%20298.15%20%7D%7B2%20%5Ctimes%2096485%7D%5Cright%20%29%20%5Cln%7B2.00%20%5Ctimes%2010%5E%7B9%7D%7D%5C%5C%5C%5C%3D%20-0.01285%20%5Ctimes%2021.41%20%3D%20%5Ctextbf%7B-0.275%20V%7D%5C%5C%5Ctext%7BThe%20cell%20potential%20for%20the%20cell%20as%20written%20is%20%7D%5Cboxed%7B%5Ctextbf%7B-0.275%20V%7D%7D)
C) is higher for nonpolar substances than for polar ones
Answer:
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Explanation:
Explanation:
Gases: more space therefore meaning that particles in the gas have the highest Kinetic energy therefore moving faster all around.
Liquid: they have more kinetic energy than liquid,but they have some space for movement so they collide each other quicker due to lack of space.
solids: They have least kinetic energy as they have no space at all meaning particles can move around and only just vibrate against each other.
Explanation:
Principal quantum number=n=7
Azimuthal quantum number=l:-
