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jeka94
3 years ago
5

Do you expect a strong chemical bond to have a higher or lower frequency than a weak bond?

Chemistry
1 answer:
Llana [10]3 years ago
6 0

Answer:

Higher frequency  

Explanation:

We can imagine a chemical bond between two atoms as if it were two balls connected by a spring.

According to Hooke's Law, the stretching frequency f is

f = \dfrac{1}{2 \pi}\sqrt{ \dfrac {k}{\mu}}

where µ is the reduced mass of the system

\mu = \dfrac{m_{1} + m_{2}}{m_{1}m_{2} }

The strength of the bond is analogous to k, the force constant of the spring. Then,

f \propto \sqrt{k}

Thus, the stronger the bond, the greater the frequency of vibration.

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[Ag^{+}]=4.2\times 10^{-2}M

Explanation:

Given:

[AgNO3] = 0.20 M

Ba(NO3)2 = 0.20 M

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Ksp of Ag2CrO4 = 1.1 x 10^-12

Ksp of BaCrO4 = 1.1 x 10^-10

BaCrO_4 (s)\leftrightharpoons  Ba^{2+}(aq)\;+\;CrO_{4}^{2-}(aq)

Ksp=[Ba^{2+}][CrO_{4}^{2-}]

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[CrO_{4}^{2-}]=\frac{1.2\times 10^{-10}}{(0.20)}= 6.0\times 10^{-10}

Now,

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Ksp=[Ag^{+}]^{2}[CrO_{4}^{2-}]

1.1\times 10^{-12}=[Ag^{+}]^{2}](6.0\times 10^{-10})

[Ag^{+}]^{2}]=\frac{1.1\times 10^{-12}}{(6.0\times 10^{-10})}= 1.8\times 10^{-3}

[Ag^{+}]=\sqrt{1.8\times 10^{-3}}=4.2\times 10^{-2}M

So, BaCrO4 will start precipitating when [Ag+] is 4.2 x 1.2^-2 M

                       

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