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ankoles [38]
3 years ago
14

Which will have the lowest boiling point?

Chemistry
2 answers:
In-s [12.5K]3 years ago
8 0

Some of the solutions exhibit colligative properties. These properties depend on the amount of

solute dissolved in a solvent. These properties include freezing point depression, boiling

point elevation, osmotic pressure and vapor pressure lowering. From the given choices, the correct answer is the first option. Pure water will have the lowest boiling point because there are no solute particles to change the boiling point of water while other options will have an elevated boiling point because of the solute.

Read more on Brainly.com - brainly.com/question/1437052#readmore

Zina [86]3 years ago
4 0

Answer: A.   pure water

Explanation:

\Delta T_b=i\times k_f\times m

\Delta T_b = change in boiling point

i = Van'T Hoff factor  

k_f = freezing point constant

m = molality

1. For pure water

, i= 1 as it is a non electrolyte and does not dissociate.

2. For 0.5M NaCl

NaCl\rightarrow Na^+Cl^-

, i= 2 , as it is a electrolyte and dissociate to give 2 ions and concentration will be (0.5+0.5)=1M[/tex]

3. For 1M NaCl

NaCl\rightarrow Na^+Cl^-

, i= 2 , as it is a electrolyte and dissociate to give 2 ions and concentration will be (1+1)=2M[/tex]

4. For 2M NaCl

NaCl\rightarrow Na^+Cl^-

, i= 2 , as it is a electrolyte and dissociate to give 2 ions and concentration will be (2+2)=4M[/tex]

Thus as vant hoff factor is lowest for pure water and thus the boiling point will be lowest.

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Complete Question

The complete question is shown on the first uploaded image

Answer:

[S]<<KM             |   [S]=KM                  |  [S]>>KM                     | Not true

____________  |   Half of the active  | Reaction rate is         | Increasing

[E_{free}] is about   |    sites are filled of  |    independent of      |  [E_{Total}] will                                            

 equal to [E_{total}]. |                                 |   [S]                             | lower KM

_____________________________________________|____________

[ES] is much       |                                 | Almost all active

 lower than         |                                 | sites are filled

[E_{free}]                  |                                 |

Explanation:

Generally the combined enzyme[ES] is mathematically represented as

                   [ES] = \frac{[E_{total}][S]}{K_M + [S]}----(1)

for Michaelis-Menten equation

Where [S] is the substrate concentration and K_M is the Michaelis constant

Considering the statement [S] < < K_M

  Looking at the equation [S] is denominator so it can be ignored(it is far too small compared to K_M)  hence the above equation becomes

               [ES] = \frac{[E_{total}][S]}{K_M}

Since [S] is less than K_M it means that \frac{[S]}{K_M}  < < 1

so it means that [ES] < < [E_{total}]

  What this means is that the  number of combined enzymes[ES] i.e the number of occupied site is very small compared to the the total sites [E_{total}]  i.e the total enzymes concentration which means that the free sites [E_{free}]  i.e the concentration of free enzymes is almost equal to [E_{total}]

Considering the second statement

      [S] = K_M

So  this means that equation one would now become

           [ES] = \frac{[E_{total}][S]}{2[S]} = \frac{[E_{total}]}{2}

So this means that half of the active sites that is the total enzyme concentration are filled with S

Considering the Third Statement

      [S] >>K_M

In this case the K_M in the denominator of equation 1 would be neglected and the equation becomes

       [ES] = \frac{[E_{total}] [S]}{[S]} = [E_{total}]

This means that almost all the sites are occupied with substrate

 The rate of this reaction is mathematically defined as

             v =\frac{V_{max}[S]}{K_M [S]}

Where v is the rate of the reaction(also know as the velocity of the reaction at a given time t) and V_{max}  is he maximum velocity of the reaction

In this case also the K_M at the denominator would be neglected as a result of the statement hence the equation becomes

                v = \frac{V_{max}[S]}{[S]} = V_{max}

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For the final statement(Not True ) it would match with condition that states that increasing [E_{total}] will lower K_M

This is because K_M does not depend on enzyme concentration it is a property of a enzyme

             

       

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