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OlgaM077 [116]
3 years ago
12

Glycine has pKa values of 2.34 and 9.60. Therefore, glycine will exist predominately as a zwitterion in an aqueous solution with

the following pH.
A. pH = 2.34 and pH = 9.60
B. pH > 2.34 and pH < 9.60
C. pH < 2.34 and pH > 9.60
D. pH = 2.34 and pH > 9.60
Chemistry
1 answer:
san4es73 [151]3 years ago
3 0

Answer:

Option (B) pH > 2.34 and pH < 9.60.

Explanation:

In a zwitterionic structure, overall negative charge should be 0.

It means, for glycine, the two functional groups e.g. -NH_{2} and -COOH should bear equal and opposite charges in it's zwitterionic structure.

pK_{a} of -COOH (in glycine) = 2.34

Therefore, at a pH > 2.34, -COOH group of glycine exists predominantly as -COO^{-}.

pK_{a} of  -NH_{2}  (in glycine) = 9.60

Therefore, at a pH < 9.60,  -NH_{2}  group of glycine exists predominantly as -NH_{3}^{+}.

Hence we can say that at 2.34 < pH < 9.60, glycine exists predominantly in zwitterionic form due to presence of -COO^{-} and -NH_{3}^{+} in equal amount.

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