<u>Answer:</u> The wavelength of spectral line is 656 nm
<u>Explanation:</u>
To calculate the wavelength of light, we use Rydberg's Equation:

Where,
= Wavelength of radiation
= Rydberg's Constant = 
= Final energy level = 2
= Initial energy level = 3
Putting the values in above equation, we get:

Converting this into nanometers, we use the conversion factor:

So, 
Hence, the wavelength of spectral line is 656 nm
We have that all (ideal) gases obey the fundamental gas equation: PV=nRT where P is the Pressure, V is the Volume, n is the number of moles, R is a universal constant and T is the temperature in Kelvin. In this process, we have that both the number of moles and the temperature stays the same. So if we denote by i the initial conditions and by f the final conditions of the gas, we have:

. Hence, if we solve for the final Volume we get:

. Now we know all the other variables; substituting we get that the final volume is 6.7 L (6.716 L ).
I did the math and i got 450 but i dont know if its right
The appropriate response is high. The best approach to consider it is those molecules have more vitality than the normal and it is unequivocally those higher enthusiastic ones that have enough vitality to break the intra-molecular forces and leave. By the way this is the reason when we sweat we chill off - the most enthusiastic molecules vanish diverting warmth.