How many kilograms of gasoline fill a 12.0-gal gas tank
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<h3><u>Full Question:</u></h3>
The following compound has been found effective in treating pain and inflammation (J. Med. Chem. 2007, 4222). Which sequence correctly ranks each carbonyl group in order of increasing reactivity toward nucleophilic addition?
A) 1 < 2 < 3
B) 2 < 3 < 1
C) 3 < 1 < 2
D) 1 < 3 < 2
<h3><u>Answer: </u></h3>The rate of nucleophilic attack of carbonyl compounds is 2<3 <1.
Option B
<h3><u>Explanation. </u></h3>Nucleophilic attack is explained as the attack of an electron rich radical to a carbonyl compound like aldehyde or a ketone. A nucleophile has a high electron density, so it searches for a electropositive atom where it can donate a portion of its electron density and become stable.
A carbonyl compound is a hybridized carbon atom with a double bonded oxygen atom in it. The oxygen atom pulls a huge portion of electron density from carbon being very electropositive.
In a ketone, there are two factors that make it less likely to undergo a nucleophilic attack than aldehyde. Firstly, the steric hindrance of two carbon groups being attached with the carbonyl carbon makes it harder for the nucleophile to approach. Secondly, the electron push by the carbon groups attached makes the carbonyl carbon a bit less electropositive than the aldehyde one. So aldehydes are more reactive towards a nucleophilic addition reaction.
Answer:
The heat of the reaction is 105.308 kJ/mol.
Explanation:
Let the heat released during reaction be q.
Heat gained by water: Q
Mass of water ,m= 1kg = 1000 g
Heat capacity of water ,c= 4.184 J/g°C
Change in temperature = ΔT = 26.061°C - 25.000°C=1.061 °C
Q=mcΔT
Heat gained by bomb calorimeter =Q'
Heat capacity of bomb calorimeter ,C= 4.643 J/g°C
Change in temperature = ΔT'= ΔT= 26.061°C - 25.000°C=1.061 °C
Q'=CΔT'=CΔT
Total heat released during reaction is equal to total heat gained by water and bomb calorimeter.
q= -(Q+Q')
q = -mcΔT - CΔT=-ΔT(mc+C)
Moles of propane =
0.0422 moles of propane on reaction with oxygen releases 4.444 kJ of heat.
The heat of the reaction will be: