To make any substance solid, molecules must come very close to each other. Substances with weak intermolecular forces have weak bonding. Hence to make their molecules come close to each other, we must provide low temperature.
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Use the clapeyron equation:
T in kelvin : 6.80 + 273 => 279.8 K
R = 0.082
n = 71.5 moles
P = 5.03 atm
Therefore:
P x V = n x R x T
5.03 x V = 71.5 x 0.082 x 279.8
5.03 x V = 1640.4674
V = 1640.4674 / 5.03
V = 326.13 L
hope ths helps!
Answer : The equilibrium concentration of
at
is,
.
Solution : Given,
Equilibrium constant, 
Initial concentration of
= 0.260 m
Let, the 'x' mol/L of
are formed and at same time 'x' mol/L of
are also formed.
The equilibrium reaction is,

Initially 0.260 m 0 0
At equilibrium (0.260 - x) x x
The expression for equilibrium constant for a given reaction is,
![K_c=\frac{[H_3O^+][C_2H_3O_2^-]}{[HC_2H_3O_2]}](https://tex.z-dn.net/?f=K_c%3D%5Cfrac%7B%5BH_3O%5E%2B%5D%5BC_2H_3O_2%5E-%5D%7D%7B%5BHC_2H_3O_2%5D%7D)
Now put all the given values in this expression, we get

By rearranging the terms, we get the value of 'x'.

Therefore, the equilibrium concentration of
at
is,
.