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Answer:
Total partial pressure, Pt = 821 mm Hg
Partial pressure of Helium, P1 = 105 mm Hg
Partial pressure of Nitrogen, P2 = 312 mm Hg
Partial pressure of Oxygen, P3 = ? mm Hg
According to Dalton's law of Partial pressures,
Pt = P1 + P2 + P3
So, <u>P3 = 404 mm Hg</u>
Given the percentage composition of HC as C → 81.82 % and H → 18.18 %
So the ratio of number if atoms of C and H in its molecule can will be:
C : H = 81.82 12 : 18.18 1 C : H = 6.82 : 18.18 = 6.82 6.82 : 18.18 6.82 = 1 : 2.66 ≈ 3 : 8
So the Empirical Formula of hydrocarbon is:
C 3 H 8
As the mass of one litre of hydrocarbon is same as that of C O 2 The molar mass of the HC will be same as that of C O 2 i.e 44 g mol
Now let Molecular formula of the HC be ( C 3 H 8 ) n
Using molar mass of C and H the molar mass of the HC from its molecular formula is:
( 3 × 12 + 8 × 1 ) n = 44 n So 44 n = 44 ⇒ n = 1
Hence the molecular formula of HC is C 3 H 8
Does that help?
