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3 years ago

If any more mix is added, it will not dissolve. the solution is

1 answer:

6 0

C. Saturated

When something is Saturated, it means that it is unable to absorb or dissolve any more of a solute at the given temperature and pressure.

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From the value Kf=1.2×109 for Ni(NH3)62+, calculate the concentration of NH3 required to just dissolve 0.016 mol of NiC2O4 (Ksp

Nina [5.8K]

Answer: The concentration of $NH_3$ required will be 0.285 M.

Explanation:

To calculate the molarity of $NiC_2O_4$ , we use the equation:

$\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}$

Moles of $NiC_2O_4$ = 0.016 moles

Volume of solution = 1 L

Putting values in above equation, we get:

$\text{Molarity of }NiC_2O_4=\frac{0.016mol}{1L}=0.016M$

For the given chemical equations:

$NiC_2O_4(s)\rightleftharpoons Ni^{2+}(aq.)+C_2O_4^{2-}(aq.);K_{sp}=4.0\times 10^{-10}$

$Ni^{2+}(aq.)+6NH_3(aq.)\rightleftharpoons [Ni(NH_3)_6]^{2+}+C_2O_4^{2-}(aq.);K_f=1.2\times 10^9$

Net equation: $NiC_2O_4(s)+6NH_3(aq.)\rightleftharpoons [Ni(NH_3)_6]^{2+}+C_2O_4^{2-}(aq.);K=?$

To calculate the equilibrium constant, K for above equation, we get:

$K=K_{sp}\times K_f\\K=(4.0\times 10^{-10})\times (1.2\times 10^9)=0.48$

The expression for equilibrium constant of above equation is:

$K=\frac{[C_2O_4^{2-}][[Ni(NH_3)_6]^{2+}]}{[NiC_2O_4][NH_3]^6}$

As, $NiC_2O_4$ is a solid, so its activity is taken as 1 and so for $C_2O_4^{2-}$

We are given:

$[[Ni(NH_3)_6]^{2+}]=0.016M$

Putting values in above equations, we get:

$0.48=\frac{0.016}{[NH_3]^6}}$

$[NH_3]=0.285M$

Hence, the concentration of $NH_3$ required will be 0.285 M.

7 0

2 years ago

Try to rationalize the sign of ΔS∘rxn in each case.

bonufazy [111]

Answer:

a) decrease, gas

b) increase, gas

c) liquid

d) increase, solid

Explanation:

Entropy refers to the degree of disorderliness of a system. If the number of moles of gas increases from left to right in a reaction, the entropy of the system increases positively.

Similarly, when the number of liquid molecules remain constant, there could only be a very little increase in entropy.

However, solids have the least entropy and the entropy of a system decreases when a system yields solid products.

6 0

2 years ago

How many particles would be found in a 89.2 g sample of Na?

julsineya [31]

One mole of a substance contains 6.02 × 10∧23 particles. Thus we first convert 89.2 g to moles. 1 mole of sodium contains 23 g
Hence 89.2 g = 89.2 / 23 g = 3.878 moles
Therefore, 3.878 × 6.02×10∧23 particles= 23.346 × 10∧23 particles
Hence 89.2 g of sodium contains 2.335 ×10∧24 particles

5 0

2 years ago

What is the role of NaCl and EDTA in DNA isolation?

alexandr402 [8]

The following is the role of NaCl and EDTA in DNA isolation, hope it helps:

NaCl provides Na+ ions that will block negative charge from phosphates on DNA. Negatively charged phosphates on DNA cause molecules to repel each other. The Na+ ions will form an ionic bond with the negatively charged phosphates on the DNA, neutralizing the negative charges and allowing the DNA molecules to come together.

4 0

2 years ago

Electromagnetic waves that are harmful to living things are

Westkost [7]

B. both high energy and low energy waves

5 0

2 years ago