Answer:
Ba has the largest atom size
S₂O₈²⁻
(aq) + 2I⁻
(aq) → I₂(aq) + 2SO₄
²⁻(aq)
2S₂O₃²⁻
(aq) + I₂(aq) → S₄O₆²⁻
(aq) + 2I⁻
(aq)
<u>Explanation:</u>
S₂O₈²⁻
(aq) + 2I⁻
(aq) → I₂(aq) + 2SO₄
²⁻(aq)
To measure the rate of this reaction we must measure the rate of concentration change of one of the reactants or products. To do this, we will include (to the reacting S₂O₈
²⁻ and I⁻
i) a small amount of sodium thiosulfate, Na₂S₂O₃,
ii) some starch indicator.
The added Na₂S₂O₃ does not interfere with the rate of above reaction, but it does consume the I₂ as soon as it is formed.
2S₂O₃²⁻
(aq) + I₂(aq) → S₄O₆²⁻
(aq) + 2I⁻
(aq)
This reaction is much faster than the previous, so the conversion of I2 back to I⁻ is essentially instantaneous.
![rate = \frac{dI2}{dt} = \frac{1/2 [S2O3^2^-]}{t}](https://tex.z-dn.net/?f=rate%20%3D%20%5Cfrac%7BdI2%7D%7Bdt%7D%20%3D%20%5Cfrac%7B1%2F2%20%5BS2O3%5E2%5E-%5D%7D%7Bt%7D)
It is really easy if you look up an electron configuration table (one that looks like a periodic table) and then just go down the rows left to right, top to bottom, and just stop when you get to where the element is on the table.
<span>M(NO3)2 ==> [M2+] + 2 [NO3-]
0.202 M ==> 0.202 M
M(OH)2 ==> [M2+] + 2[OH-]
5.05*10^-18 ===> s + [2s]^2
5.05*10^-18 ===> 0.202 + [2s]^2
5.05*10^-18 = 0.202 * 4s^2
4s^2 = 25*10^-18
s^2 = 6.25*10^-18
s = 2.5*10^-9
So, the solubility is 2.5*10^-9</span>
The answer is (4) taxing the colonies without representation in Parliament
This set off the Revolutionary War, and the slogan "no taxation without representation" became famous.