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FrozenT [24]
3 years ago
5

Iron-59 is a beta emitter with a half-life of 44.5 days. If a sample initially contains 180 mg of iron-59, how much iron-59 is l

eft in the sample after 267 days?
Chemistry
1 answer:
Jobisdone [24]3 years ago
5 0

Answer:

2.79 mg iron-59 is left in the sample after 267 days.

Explanation:

Given that:

Half life = 44.5 days

t_{1/2}=\frac {ln\ 2}{k}

Where, k is rate constant

So,  

k=\frac {ln\ 2}{t_{1/2}}

k=\frac {ln\ 2}{44.5}\ days^{-1}

The rate constant, k = 0.0156 days⁻¹

Using integrated rate law for first order kinetics as:

[A_t]=[A_0]e^{-kt}

Where,  

[A_t] is the concentration at time t

[A_0] is the initial concentration  = 180 mg

Time = 267 days

So,  

[A_t]=180\ mg\times e^{-0.0156\times 267}

[A_t]=180\times e^{-0.0156\times 267}\ mg

[A_t]=2.79\ mg

<u>2.79 mg iron-59 is left in the sample after 267 days.</u>

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A solution of phosphoric acid was made by dissolving 10.8 g of H3PO4 in 133.00 mL of water. The resulting volume was 137 mL. Cal
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Answer:

Density is: 1.05 g/ml

Mole fraction solute: 0.015

Mole fraction solvent:  0.095

Molarity: 0.80 M

Molality: 0.82 m

Explanation:

A typical excersise of solution.

It is more confortable to make a table for this.

                |   masss  |  volume  |  mol

solute       |                |                |          

solvent     |                |                |  

solution    |                |                |

Let's complete, what we have.

                 |   masss  |  volume  |  mol

solute       |  10.8g     |                |          

solvent     |                |  133 mL   |  

solution    |                |  137 mL    |

We can first, know how many moles are 10.8 g

Molar Mass H3PO4 = 97.99 g/mol

Mass / Molar mass = mol

10.8 g / 97.99 g/m = 0.110 mol

Density of water is 1 g/ml (it is a very knowly value)

From this data, we can know water mass, solvent.

Density = mass / volume

1 g/ml = mass / 133 mL

Mass = 133 g

We can also have the moles, by the molar mass of water 18 g/m

133 g / 18 g/m = 7.39 mol

                 |   masss  |  volume  |  mol

solute       |   10.8g     |                |   0.110 mol      

solvent     |   133g      |  133 mL   |  7.39 mol

solution    |   143.8g   |  137 mL   | 7.50 mol

Mass of solution will be solute mass + solvent mass

Moles of solution will be solute moles + solvent moles

Now we can calculate everything.

Molarity means mol of solute in 1 L of solution. (mol/L)

We have to convert 137 mL in L (/1000)

0.137L so → 0.110 m / 0.137L = 0.80 M

Molality means mol of solute in 1kg of solvent.

We have to convert 133g in kg (/1000)

0.133 kg so → 0.110 m/0.133 kg = 0.82 m

Density is mass / volume

Solution density will be solution mass / solution volume

143.8 g/137 mL = 1.05 g/m

Molar fraction is : solute moles / total moles  or  solvent moles/total moles.

You can also (x 100%) to have a percent of them.

Remember sum of molar fraction = 1

Molar fraction of solute = 0.110 mol / 7.50mol = 0.015

Molar fraction of solvent = 7.39 mol / 7.50 mol = 0.985

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