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9966 [12]
3 years ago
5

Describe the difference between intensive and extensive propoerties. Which of the following propoerties are intensive: (a) mass;

(b) density; (c) volume; (d) melting point
Chemistry
1 answer:
STatiana [176]3 years ago
4 0

Answer:

The properties <u>that </u><u>do not vary</u><u> with the variation in the quantity of the material are called as </u><u>intensive property</u>.

While the <u>extensive properties</u><u> are those which </u><u>vary with the variation in the quantity of the material</u>.

Intensive properties:

Mass and volume

Extensive properties:

Density and melting point

Explanation:

The properties <u>that </u><u>do not vary</u><u> with the variation in the quantity of the material are called as </u><u>intensive property</u>.

While the <u>extensive properties</u><u> are those which </u><u>vary with the variation in the quantity of the material</u>.

Intensive properties:

Mass and volume, as with increase in quantity of the material mass and volume increases.

Extensive properties:

Density and melting point, as they remain constant for a object or material

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3 years ago
Which of these is correct?
Viktor [21]

Answer:

1.89 nol Cu(NO3)2

Explanation:

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5 0
2 years ago
Estimate the coordination number for the cations in each of these ceramic oxides and also the coordination numbers of the oxygen
Juli2301 [7.4K]

Answer:

CN cation, anion ] respectively are thus [6,4] , [2,3] ,[6,6] , [6,6] , [6,3] , [12,6,2] , [6], [6].

Explanation:

The coordination number CN is the number of ligand atoms bonded (coordinate bonds) directly to the central of the metal ion. It is not the same as the oxidation state of the metal ion or complex.

Coordination number – the number of anions surrounding the cation.

In solving for CN we need to understand Pauling's rules.

According to Linus Pauling, 1932

“Pauling’s rules” for crystal structures, makes assumptions for ionic bonding. It states that ionic structure is understood using electrostatic rules of attraction and repulsion.

Cations and anions surround each other to neutralize charge – and these one can rationalize crystal structure with coordination number.

Ratio of cationic/anionic radius

• The structure of D-Al2O3 results in coordination number of 6 and 4 for cation and anion respectively.

• The average oxygen coordination number in v-B2O3 is equal to the average cation coordination number × cation/anion ratio (2/3).

• Co-ordination number of Ca2+ ion is =6;

In CaO crystal, Ca2+ is a cation and O2- is an anion. Cationic (Ca2+) has radius 100 pm and anionic (O2-) has radius  145 pm.

Ratio of cationic/anionic radius is:

r⁺/r⁻ = 100 / 145

r⁺/r⁻ = 0.69

CaO will form FCC lattice.

Coordination number in FCC lattice is 6. Therefore CN of Ca2+ = 6.

For MgO:

r Mg2+/ r O2- = 86pm / 126 pm =0.683

The cordination number for the cation is 6. MgO with ions Mg+2 and O-2 will have a AX type stochiometry exhibiting the

crystal structure of sodium chloride.

For TiO2:

The CN of the titanium (IV) cation is 6, which is twice the CN of the oxide anion, which is 3.

This fits with the formula unit of TiO2, since there are twice as many O2− ions as Ti4+ ions.

Consequently the crystal structure of all ionic compounds reflects the formula unit.

For LaAlO3 a Cubic perovskites (ABX3)

In perovskite structures, B cations are coordinated by six X anions, while A

cations present CN = 12 (also coordinated by X anions). The X anions have CN = 2, being

coordinated by two A cations, since the distance A-O is about 40% larger than the B-O

bond distance. The correct ionic radii (rA, rB, rX), taken from one of Shannon’s work.

rA = 1.36 pm

rB = 0.535 pm

rX = 1.35 pm

Forsterite Mg2SiO4

We have mixed sites of Si4+ in tetrahedral site, Mg2+ in octahedral site, O atoms anions .

They all forms octahedral chains/strips. The CN is estimated to (6) octahedral, with an average ratio 0.414

Nickel Cobaltite Ni(Co2O4)3

bidentate ligand includes the Oxalate, three oxalate ligands form six-coordinate bonds around the Ni2+ ion.

Co-ordinate number of Nickel in [Ni(C2​O4​)3​] 4− is 3×2=6.

5 0
3 years ago
A 32.5 g iron rod, initially at 22.4 ∘C, is submerged into an unknown mass of water at 63.0 ∘C, in an insulated container. The f
Allisa [31]

Answer:

The mass of water m_{w} = 39.18 gm

Explanation:

Mass of iron m_{iron} = 32.5 gm

Initial temperature of iron T_{1} = 22.4°c = 295.4 K

Specific heat of iron  C_{iron} = 0.448 \frac{KJ}{kg K}

Mass of water = m_{w}

Specific heat of water  C_{w} = 4.2 \frac{KJ}{kg  K}

Initial temperature of water T_{2} = 336 K  

Final temperature after equilibrium T_{f} = 59.7°c = 332.7 K

When iron rod is submerged into water then

Heat lost by water  = Heat gain by iron rod

m_{w} C_{w} (T_{2} - T_{f} ) =  m_{iron} C_{iron} ( T_{f} - T_{1} )

Put all the values in above formula we get

m_{w} × 4.2 × ( 336 - 332.7 ) = 32.5 × 0.448 × ( 332.7 - 295.4 )

m_{w} = 39.18 gm

Therefore the mass of water m_{w} = 39.18 gm

8 0
3 years ago
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