Answer:
A. Diethyl ether will react with the alkenes that were formed in the experiment.
Explanation:
Ethers such as diethyl ether dissolve a wide range of polar and nonpolar organic compounds. Nonpolar compounds are generally more soluble in diethyl ether than alcohols because ethers do not have a hydrogen bonding network that must be broken up to dissolve the solute.
Answer:
HOAc is stronger acid than HClO
ClO⁻ is stronger conjugate base than OAc⁻
Kb(OAc⁻) = 5.5 x 10⁻¹⁰
Kb(ClO⁻) = 3.3 x 10⁻⁷
Explanation:
Assume 0.10M HOAc => H⁺ + OAc⁻ with Ka = 1.8 x 10⁻⁵
=> [H⁺] = √Ka·[Acid] =√(1.8 x 10⁻⁵)(0.10) M = 1.3 x 10⁻³M H⁺
Assume 0.10M HClO => H⁺ + ClO⁻ with Ka = 3 x 10⁻⁸
=> [H⁺] = √(3 x 10⁻⁸)(0.10)M = 5.47 x 10⁻⁵M H⁺
HOAc delivers more H⁺ than HClO and is more acidic.
Kb = Kw/Ka, Kw = 1 x 10⁻¹⁴
Kb(OAc⁻) = 5.5 x 10⁻¹⁰
Kb(ClO⁻) = 3.3 x 10⁻⁷
Answer:
The Order is as follow,
C-H < S-H < H-Br < H-Cl
Explanation:
Polarity depends on the electronegativity difference between two atoms, greater the electronegativity difference, greater will be the polarity of bond and vice versa.
Electronegativity Difference between Hydrogen and other given elements are as follow,
1) C-H;
E.N of Carbon = 2.55
E.N of Hydrogen = 2.20
------------
Difference 0.35
2) S-H;
E.N of Sulfur = 2.58
E.N of Hydrogen = 2.20
------------
Difference 0.38
3) H-Br;
E.N of Bromine = 2.96
E.N of Hydrogen = 2.20
-------------
Difference 0.76
4) H-Cl;
E.N of Chlorine = 3.16
E.N of Hydrogen = 2.20
-----------
Difference 0.96
Hence it is proved that the greatest electronegativity difference is found between H and Chlorine in H-Cl, therefore it is highly polar bond and vice versa.
Answer:
All three are present
Explanation:
Addition of 6 M HCl would form precipitates of all the three cations, since the chlorides of these cations are insoluble: 
.
- Firstly, the solid produced is partially soluble in hot water. Remember that out of all the three solids, lead(II) choride is the most soluble. It would easily completely dissolve in hot water. This is how we separate it from the remaining precipitate. Therefore, we know that we have lead(II) cations present, as the two remaining chlorides are insoluble even at high temperatures.
- Secondly, addition of liquid ammonia would form a precipitate with silver:
![AgCl (s) + 2 NH_3 (aq) + H_2O (l)\rightarrow [Ag(NH_3)_2]OH (s) + HCl (aq)](https://tex.z-dn.net/?f=AgCl%20%28s%29%20%2B%202%20NH_3%20%28aq%29%20%2B%20H_2O%20%28l%29%5Crightarrow%20%5BAg%28NH_3%29_2%5DOH%20%28s%29%20%2B%20HCl%20%28aq%29)
; Silver hydroxide at higher temperatures decomposes into black silver oxide: ![2 [Ag(NH_3)_2]OH (s)\rightarrow Ag_2O (s) + H_2O (l) + 4 NH_3 (g)](https://tex.z-dn.net/?f=2%20%5BAg%28NH_3%29_2%5DOH%20%28s%29%5Crightarrow%20Ag_2O%20%28s%29%20%2B%20H_2O%20%28l%29%20%2B%204%20NH_3%20%28g%29)
. - Thirdly, we also know we have
in the mixture, since addition of potassium chromate produces a yellow precipitate: 
. The latter precipitate is yellow.
