Question

Determine the percent ionization of a 0.225 M solution of benzoic acid. Express your answer using two significant figures.

Answer 1

Answer:

1.68% is ionized

Explanation:

The Ka of benzoic acid, C₇H₆O₂, is 6.46x10⁻⁵, the equilibrium in water of this acid is:

C₇H₆O₂(aq) + H₂O(l) ⇄ C₇H₅O₂⁻(aq) + H₃O⁺(aq)

Ka = 6.46x10⁻⁵ = [C₇H₅O₂⁻] [H₃O⁺] / [C₇H₆O₂]

Where [] are concentrations in equilibrium

In equilibrium, some 0.225M of the acid will react producing both C₇H₅O₂⁻ and H₃O⁺, the equilibrium concentrations are:

[C₇H₆O₂] = 0.225-X

[C₇H₅O₂⁻] = X

[H₃O⁺] = X

Replacing:

6.46x10⁻⁵ = [X] [X] / [0.225-X]

1.4535x10⁻⁵ - 6.46x10⁻⁵X = X²

1.4535x10⁻⁵ - 6.46x10⁻⁵X - X² = 0

Solving for X:

X = -0.0038. False solution, there is no negative concentrations.

X = 0.00378M. Right solution.

That means percent ionization (100 times Amount of benzoic acid ionized  over the initial concentration of the acid) is:

0.00378M / 0.225M * 100 =

1.68% is ionized