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Dennis_Churaev [7]
3 years ago
5

For the following systems at equilibrium C: CaCO3(s) ⇌ CaO(s)+CO2(g) ΔH=+178 kJ/mol D: PCl3(g)+Cl2(g) ⇌ PCl5(g) ΔH=−88 kJ/mol cl

assify these changes by their effect: System C - Increase temperature. System D - Increase temperature. System C - Decrease temperature. System D - Decrease temperature.
Chemistry
1 answer:
Rama09 [41]3 years ago
7 0

Explanation:

C: CaCO_3(s)\rightleftharpoons CaO(s)+CO_2(g)ΔH=+178 kJ/mol

For an endothermic reaction, heat is getting absorbed during a chemical reaction and is written on the reactant side.

A+\text{heat}\rightleftharpoons B

Any change in the equilibrium is studied on the basis of Le-Chatelier's principle.  This principle states that if there is any change in the variables of the reaction, the equilibrium will shift in the direction to minimize the effect.

Treat heat as a reactant and on increasing a reactant at equilibrium, shifts the reaction in the forward direction.

Increase temperature →  increase in heat → forward direction

Decrease temperature →  decease in heat → backward direction

System C - Increase temperature : Reaction will move forward

System C - Decrease temperature : Reaction will move backward

D: PCl_3(g)+Cl_2(g)\rightleftharpoons PCl_5(g) ΔH=−88 kJ/mol

The total enthalpy of the reaction comes out to be negative .

The temperature of the surrounding will increase.

For an exothermic reaction, heat is released during a chemical reaction and is written on the product side.

A\rightleftharpoons B+\text{ heat}

Any change in the equilibrium is studied on the basis of Le-Chatelier's principle.  This principle states that if there is any change in the variables of the reaction, the equilibrium will shift in the direction to minimize the effect.

Treat heat as a product and on increasing a product at equilibrium, shifts the reaction in the backward direction.

Increase temperature →  increase in heat → backward direction

Decrease temperature →  decease in heat → forward direction

System D - Increase temperature : Reaction will move backward

System D - Decrease temperature : Reaction will move forward

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ΔH°_f/(kJ·mol⁻¹):    -45.9          0                 0        -241.8

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ΔH°_rxn =  (-1450.8 + 183.6) kJ = -1267.2 kJ

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