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ira [324]
3 years ago
9

What is the concentration (in M) of a 225ml potassium sulfate solution that contains 4.15g of potassium?

Chemistry
1 answer:
mars1129 [50]3 years ago
4 0

The concentration of solution in M or mol/L can be calculated using the following formula:

C=\frac{n}{V} .... (1)

Here, n is number of moles and V is volume of solution in L.

The molecular formula of potassium sulfate is K_{2}SO_{4} thus, there are 2 moles of potassium in 1 mol of potassium sulfate.

1 mol of potassium will be there in 0.5 mol of potassium sulfate.

Mass of potassium is 4.15 g, molar mass is 39.1 g/mol.

Number of moles can be calculated as follows:

n=\frac{m}{M}

Here, m is mass and M is molar mass

Putting the values,

n=\frac{(4.15 g}{(39.1 g/mol}=0.1061 mol

Thus, number of moles of  K_{2}SO_{4} will be 0.1061\times 0.5=0.053 mol.

The volume of solution is 225 mL, converting this into L,

1 mL=10^{-3}L

Thus,

225 mL=0.225 L

Putting the values in equation (1),

C=\frac{(0.053 mol}{0.225 L}=0.236 M

Therefore, concentration of potassium sulfate solution is 0.236 M.


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Hess’s law of constant heat summation states that the amount of heat absorbed or evolved in a given chemical equation remains the same whether the process occurs in one step or several steps.

According to this law, the chemical equation is treated as ordinary algebraic expressions and can be added or subtracted to yield the required equation. This means that the enthalpy change of the overall reaction is equal to the sum of the enthalpy changes of the intermediate reactions.

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The expression for enthalpy of the reaction follows:

\Delta H^o_{rxn}=[1\times (\Delta H_1)]+[2\times (-\Delta H_2)]+[2\times (\Delta H_3)]

Putting values in above equation, we get:

\Delta H^o_{rxn}=[(1\times (-1184))+(2\times -(-234))+(2\times (394))]=72kJ

Hence, the \Delta H^o_{rxn} for the reaction is 72 kJ.

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