c. a tertiary alcohol; when a ketone reacts with a grignard reagent followed by protonation a tertiary alcohol is formed.
More about tertiary alcohol:
No hydrogen atoms are bonded to the functional group's carbon in a tertiary alcohol. Alcohols that have a hydroxyl group bonded to the carbon atom and are linked to three alkyl groups are referred to as tertiary alcohols. These alcohols' structural makeup largely determines their physical characteristics.
This -OH group's existence enables alcohols to create hydrogen bonds with the atoms next to them. Because of this weak connection, alcohols have higher boiling points than their alkane counterparts.
The alcohol is referred to as a tertiary (3°) alcohol if the carbon atom carrying the alcohol group is connected to three other carbon atoms in the alcohol molecule.
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This is called the pedigree chart.
The pH a 0.25 m solution of C₆H₅NH₂ is equal to 3.13.
<h3>How do we calculate pH of weak base?</h3>
pH of the weak base will be calculate by using the Henderson Hasselbalch equation as:
pH = pKb + log([HB⁺]/[B])
pKb = -log(1.8×10⁻⁶) = 5.7
Chemical reaction for C₆H₅NH₂ is:
C₆H₅NH₂ + H₂O → C₆H₅NH₃⁺ + OH⁻
Initial: 0.25 0 0
Change: -x x x
Equilibrium: 0.25-x x x
Base dissociation constant will be calculated as:
Kb = [C₆H₅NH₃⁺][OH⁻] / [C₆H₅NH₂]
Kb = x² / 0.25 - x
x is very small as compared to 0.25, so we neglect x from that term and by putting value of Kb, then the equation becomes:
1.8×10⁻⁶ = x² / 0.25
x² = (1.8×10⁻⁶)(0.25)
x = 0.67×10⁻³ M = [C₆H₅NH₃⁺]
On putting all these values on the above equation of pH, we get
pH = 5.7 + log(0.67×10⁻³/0.25)
pH = 3.13
Hence pH of the solution is 3.13.
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