According to Raoult's law, Vapor pressure is directly proportional to the mole fraction of the solution. As 1.0 M CaF2 has least moles here, it has lowest vapor pressure.
In short, Your Answer would be Option D
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The similarity of the bands in the crystal of a metal to the atomic orbitals can be explained by the band theory of metals. In an atom, when the electrons get excited, the electrons jumps to a higher orbital so as to reach equilibrium. This is analogous to the electrons in the metals which also jumps to another band once excited by an external energy (e.g. electrical energy).
Answer: penetration is the ability of an electron in a given orbital to approach the nucleus closely. Shielding refers to the fact that core electrons reduce the degree of nuclear attraction felt by the orbital electrons. Shielding is the opposite of penetration. The most penetrating orbital is the least screening orbital. The order of increasing shielding effect/decreasing penetration is s<p<d<f.
Explanation:
The order of penetrating power is 1s>2s>2p>3s>3p>4s>3d>4p>5s>4d>5p>6s>4f....
Since the 3p orbital is more penetrating than the 3d orbital, it will lie nearer to the nucleus and thus possess lower energy.