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Kitty [74]
3 years ago
6

Given the system at equilibrium:

Chemistry
1 answer:
emmasim [6.3K]3 years ago
5 0
<span>(4) The equilibrium shifts to the left and the concentration of PCl3(g) decreases.

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At a certain concentration of H2 and I2, the initial rate of reaction is 4.0 x 104 M / s. What would the initial rate of the rea
andreev551 [17]

The question is incomplete, here is the complete question:

The rate of certain reaction is given by the following rate law:

rate=k[H_2]^2[I_2]^2

At a certain concentration of H_2 and I_2, the initial rate of reaction is 4.0 × 10⁴ M/s. What would the initial rate of the reaction be if the concentration of

Answer : The initial rate of the reaction will be, 1.0\times 10^4M/s  

Explanation :

Rate law expression for the reaction:

rate=k[H_2]^2[I_2]^2

As we are given that:

Initial rate = 4.0 × 10⁴ M/s

Expression for rate law for first observation:

4.0\times 10^4=k[H_2]^2[I_2]^2 ....(1)

Expression for rate law for second observation:

R=k(\frac{[H_2]}{2})^2[I_2]^2 ....(2)

Dividing 2 by 1, we get:

\frac{R}{4.0\times 10^4}=\frac{k(\frac{[H_2]}{2})^2[I_2]^2}{k[H_2]^2[I_2]^2}

\frac{R}{4.0\times 10^4}=\frac{1}{4}

R=1.0\times 10^4M/s

Therefore, the initial rate of the reaction will be, 1.0\times 10^4M/s

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