Answer: Because it's a combination of chemicals, vodka doesn't freeze at the same temperature as either water or alcohol. Of course, vodka will freeze, but not at the temperature of an ordinary freezer. This is because vodka contains enough alcohol to lower the freezing point of water below the -17°C of your typical freezer.
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The answer is dilute. A dilute salt solution contains a small amount of salt with high water concentration while a concentrated salt solution has a large amount of salt with a lower water concentration. Salt is inorganic hence it is not monounsaturated, which is a term related to organic compounds. The salt is unable to dissolve anymore in a saturated salt solution, leaving the undissolved salt at the bottom and this is not the case here since we only have a small amount of salt.