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Cloud [144]
3 years ago
12

Chlorine has two naturally occuring isotopes - chlorine-35 and chlorine-37. Elaborate on how the atomic mass is determined given

that chlorine-35 has an abundance of 75.78% and has a mass of 34.969 amu and that chlorine-37 has an abundance of 24.22% and a mass of 36.966 amu.
Chemistry
1 answer:
Soloha48 [4]3 years ago
4 0
Because the gmm for chlorine is 35.5 which is the average of all of those combined, so the percentages reflect how much of each isotope is needed to make the average that specific mass per mole
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Atom 1 and 4 because they have the same number of valence elctrons in its outermost shell

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Pentaborane-9, B5H9, is a colorless, highly reactive liquid that will burst into flame when exposed to oxygen. The reaction is 2
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<u>Answer:</u> The amount of energy released per gram of B_5H_9 is -71.92 kJ

<u>Explanation:</u>

For the given chemical reaction:

2B_5H_9(l)+12O_2(g)\rightarrow 5B_2O_3(s)+9H_2O(l)

The equation used to calculate enthalpy change is of a reaction is:  

\Delta H^o_{rxn}=\sum [n\times \Delta H^o_f_{(product)}]-\sum [n\times \Delta H^o_f_{(reactant)}]

The equation for the enthalpy change of the above reaction is:

\Delta H^o_{rxn}=[(5\times \Delta H^o_f_{(B_2O_3(s))})+(9\times \Delta H^o_f_{(H_2O(l))})]-[(2\times \Delta H^o_f_{(B_5H_9(l))})+(12\times \Delta H^o_f_{(O_2(g))})]

Taking the standard enthalpy of formation:

\Delta H^o_f_{(B_2O_3(s))}=-1271.94kJ/mol\\\Delta H^o_f_{(H_2O(l))}=-285.83kJ/mol\\\Delta H^o_f_{(B_5H_9(l))}=73.2kJ/mol\\\Delta H^o_f_{(O_2(g))}=0kJ/mol

Putting values in above equation, we get:

\Delta H^o_{rxn}=[(5\times (1271.94))+(9\times (-285.83))]-[(2\times (73.2))+(12\times (0))]\\\\\Delta H^o_{rxn}=-9078.57kJ

We know that:

Molar mass of pentaborane -9 = 63.12 g/mol

By Stoichiometry of the reaction:

If 2 moles of B_5H_9 produces -9078.57 kJ of energy.

Or,

If (2\times 63.12)g of B_5H_9 produces -9078.57 kJ of energy

Then, 1 gram of B_5H_9 will produce = \frac{-9078.57kJ}{(2\times 63.12)}\times 1g=-71.92kJ of energy.

Hence, the amount of energy released per gram of B_5H_9 is -71.92 kJ

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