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QveST [7]
2 years ago
9

Enter the number of unique signals in the 1H NMR spectrum of ethanol. Assume that the hydroxy proton does NOT exchange with the

NMR solvent.
Chemistry
1 answer:
ss7ja [257]2 years ago
5 0

Answer:

In the 1H NMR spectrum of ethanol three different signals are observed, this is due to the existence of 3 types of hydrogens with different chemical environment. Hydrogens A (3.57 ppm) are more screened than C (1.10 ppm) due to the presence of oxygen (electonegative atom that removes electron density). The chemical environment of hydrogen B (4.78 ppm), attached directly to oxygen, is also different by resonating at a frequency different from the previous ones.

C1HC_{3} -C2HA_{2} -OHB

The hydroxylic hydrogen produces a singlet, the pair of carbon hydrogens one give rise to a quadruplet and the three hydrogens of carbon two produce a triplet.

Explanation:

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Calculate the cell potential at 25oC under the following nonstandard conditions: 2MnO4-(aq) + 3Cu(s) + 8H+(aq) ⟶ 2MnO2(s) + 3Cu2
baherus [9]

Answer:

1.346 v

Explanation:

1) Fist of all we need to calculate the standard cell potential, one should look up the reduction potentials for the species envolved:

(oxidation) Cu_{(s)} →Cu^{2+}_{(aq)} +2e E°=0.337 v

(reduction) MnO_{4 (aq)} + 3e + 4H^{+}_{(aq)}→MnO_{2 (aq)}+2H_{2}O E°=1.679 v

(overall) 2MnO_{4 (aq)}+3Cu_{(s)}+8H^{+}_{(aq)}→3Cu^{2+}_{(aq)}+2MnO_{2 (aq)}+4H_{2}O E°=1.342 v

2) Nernst Equation

Knowing the standard potential, one calculates the nonstandard potential using the Nernst Equation:

E=E^{0} -\frac{RT}{nF}Ln\frac{[red]}{[ox]}

Where 'R' is the molar gas constant, 'T' is the kelvin temperature, 'n' is the number of electrons involved in the reaction and 'F' is the faraday constant.

The problem gives the [red]=0.66M and [ox]=1.69M, just apply to the Nernst Equation to give

E=1.342 -\frac{298.15*8.314}{6*96500}Ln\frac{[.66]}{[1.69]}=1.346

E=1.346

5 0
2 years ago
. How many grams of NaOH would you need to make 450 mL of a 0.250 M NaOH solution
Stella [2.4K]
You have molarity and you have volume. Use the formula :
Molarity(M)= Moles(N)/Liter(L)            to get the solution. 
450 ml= .450 L
.250 = N/.450
N=.1125 moles of NaOH.
 And since you know the moles, use the molar mass to figure out the grams.
<span> (40g/mol NaOH) x (.1125 mol) =  
4.5g of NaOH.
</span>
Hope it helps. Good luck on chemistry.
7 0
3 years ago
How do the ionic radii vary within a group of non-metals?
stellarik [79]

Answer: Ionic radii is half the distance between two ions.

Explanation: from top to bottom down an element group, ionic radius increases. This is because a new electron shell is added as you move down the periodic table.

Might Be wrong not sure :)

8 0
3 years ago
How many atoms of Na are in 1.89 mol of Na?
atroni [7]

Answer:

1.138158E24 atoms or 1.14 x 10^24 atoms

Explanation:

To find atoms/particles from moles you just want to convert using avogadro's number which is 6.022 x 10^23

1.89 mol x 6.022 • 10^23

———— = 1.138158E24 atoms

1 mol

so 1.138158E24 atoms or 1.14 x 10^24 for scientific notation

hope this helps :)

5 0
2 years ago
If an object has two forces acting on it how can the next force equal 0
Flura [38]

If the forces are equal and in opposite directions, the net force will equal zero.

Consider a tug-of-war team. If they are pulling with equal forces against each other, the red cloth on the rope will not move.

<em>F = ma </em>

The cloth is not moving, so <em>a = </em>0 and the net force <em>F = </em>0.

6 0
3 years ago
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