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stepan [7]
3 years ago
9

The oxidation of methanol to formaldehyde can be accomplished by reaction with chromic acid: 6H+ + 3CH3OH + 2H2CrO4 → 3CH2O + 2C

r3+ + 8 H2O(l) The reaction can be studied with the stable isotope tracer 18O and mass spectrometry. When a small amount of CH318OH is present in the alcohol reactant, CH218O forms. When a small amount of H2Cr18O4 is present, H218O forms. Does chromic acid or methanol supply the O atom to the aldehyde?

Chemistry
1 answer:
babunello [35]3 years ago
7 0

Lo que está marcado con rojo (el ejercicio)

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) Do you think the pH of 1,0 M tri-methyl ammonium (CH3)3NH+, pKa = 9.80, will be higher or lower than that of 1.0 M phenol, C6H
Elanso [62]

Answer:

1. The pH of 1.0 M trimethyl ammonium (pH = 1.01) is lower than the pH of 0.1 M phenol (5.00).

2. The difference in pH values is 4.95.

Explanation:

1. The pH of a compound can be found using the following equation:

pH = -log([H_{3}O^{+}])

First, we need to find [H₃O⁺] for trimethyl ammonium and for phenol.

<u>Trimethyl ammonium</u>:

We can calculate [H₃O⁺] using the Ka as follows:

(CH₃)₃NH⁺ + H₂O  →  (CH₃)₃N + H₃O⁺    

1.0 - x                               x           x  

Ka = \frac{[(CH_{3})_{3}N][H_{3}O^{+}]}{[(CH_{3})_{3}NH^{+}]}

10^{-pKa} = \frac{x*x}{1.0 - x}

10^{-9.80}(1.0 - x) - x^{2} = 0    

By solving the above equation for x we have:  

x = 0.097 = [H₃O⁺]

pH = -log([H_{3}O^{+}]) = -log(0.097) = 1.01                                      

<u>Phenol</u>:

C₆H₅OH + H₂O → C₆H₅O⁻ + H₃O⁺

1.0 - x                        x             x

Ka = \frac{[C_{6}H_{5}O^{-}][H_{3}O^{+}]}{[C_{6}H_{5}OH]}

10^{-10} = \frac{x^{2}}{1.0 - x}

1.0 \cdot 10^{-10}(1.0 - x) - x^{2} = 0

Solving the above equation for x we have:

x = 9.96x10⁻⁶ = [H₃O⁺]

pH = -log([H_{3}O^{+}]) = -log(9.99 \cdot 10^{-6}) = 5.00

Hence, the pH of 1.0 M trimethyl ammonium is lower than the pH of 0.1 M phenol.

2. The difference in pH values for the two acids is:

\Delta pH = pH_{C_{6}H_{5}OH} - pH_{(CH_{3})_{3}NH^{+}} = 5.00 - 1.01 = 4.95

Therefore, the difference in pH values is 4.95.

I hope it helps you!

7 0
4 years ago
25) Which of the following would exert the most pressure on the ground? 3 points
Zarrin [17]

Answer:

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Explanation:

8 0
3 years ago
Read 2 more answers
How does doubling the volume of solvent affect the concentration of the solution?
Alex17521 [72]

Answer:

Molarity is halved when the volume of solvent is doubled.

Explanation:

Using the dilution equation (volume 1)(molarity 1)=(volume 2)(molarity 2), we can demonstrate the effects of doubling volume.

Suppose the starting volume is 1 L and the starting molarity is 1 M, and doubling the volume would make the final volume 2 L.

Plugging these numbers into the equation, we can figure out the final molarity.

(1 L)(1 M)=(2 L)(X M)

X M= (1 L x 1 M)/(2 L)

X M= 1/2 M

This shows that the molarity is halved when the volume of solvent is doubled.

8 0
3 years ago
Give two examples of how our society uses isotopes
nalin [4]

Answer:

Isotopes – caused by varying numbers of neutrons in an element – have many practical uses in our society. ... In geology and archaeology, radioactive isotopes are used to determine the age of a sample while hydrologists can use isotope signatures to distinguish between different groundwater types.

Explanation:

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6 0
3 years ago
An unknown metal sulfate is found to be 72.07% SO4 2- by mass. Assuming that the charge on the metal cation is +3, determine the
wariber [46]
Lets name the unknown metal as M. Cation would be M³⁺.
the molecular formula of the compound is M₂(SO₄)₃
the mass of one mole - (molar mass of M x2 + 3 x molar mass of SO₄²⁻)
                                   = 2M + 96 x 3
                                   = 2M + 288
In 1 mol if there's 72.07% of sulphate , 
then 72.07 % corresponds to 288 g
               1 % is then      - 288/72.07 
       100 %  of the compound - 288/72.07 x 100 
 molar mass of the compound - 399.6 g/mol
mass of 2M - 399.6 - 288 = 111.6 g
molar mass of M - 111.6 /2 = 55.8 g/mol
the element with molar mass of 55.8 is Fe.
Unknown metal is iron(III) , Fe³⁺

8 0
3 years ago
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