The enthalpy of reaction for the combustion of ethane 2CH₃CH₃ + 7O₂ → 4CO₂ + 6H₂O calculated from the average bond energies of the compounds is -2860 kJ/mol.
The reaction is:
2CH₃CH₃ + 7O₂ → 4CO₂ + 6H₂O (1)
The enthalpy of reaction (1) is given by:
(2)
Where:
r: is for reactants
p: is for products
The bonds of the compounds of reaction (1) are:
- 2CH₃CH₃: 2 moles of 6 C-H bonds + 2 moles of 1 C-C bond
- 7O₂: 7 moles of 1 O=O bond
- 4CO₂: 4 moles of 2 C=O bonds
- 6H₂O: 6 moles of 2 H-O bonds
Hence, the enthalpy of reaction (1) is (eq 2):
![\Delta H = [2*(6*413 + 347) + 7*498 - (4*2*799 + 6*2*467)] kJ/mol](https://tex.z-dn.net/?f=%20%5CDelta%20H%20%3D%20%5B2%2A%286%2A413%20%2B%20347%29%20%2B%207%2A498%20-%20%284%2A2%2A799%20%2B%206%2A2%2A467%29%5D%20kJ%2Fmol%20)
Therefore, the enthalpy of reaction for the combustion of ethane is -2860 kJ/mol.
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Answer:
131.5 kJ
Explanation:
Let's consider the following reaction.
CaCO₃(s) → CaO(s) + CO₂(g)
First, we will calculate the standard enthalpy of the reaction (ΔH°).
ΔH° = 1 mol × ΔH°f(CaO(s)) + 1 mol × ΔH°f(CO₂(g)
) - 1 mol × ΔH°f(CaCO₃(s)
)
ΔH° = 1 mol × (-634.9 kJ/mol) + 1 mol × (-393.5 kJ/mol) - 1 mol × (-1207.6 kJ/mol)
ΔH° = 179.2 kJ
Then, we calculate the standard entropy of the reaction (ΔS°).
ΔS° = 1 mol × S°(CaO(s)) + 1 mol × S°(CO₂(g)
) - 1 mol × S°(CaCO₃(s)
)
ΔS° = 1 mol × (38.1 J/mol.K) + 1 mol × (213.8 J/mol.K) - 1 mol × (91.7 J/mol.K)
ΔS° = 160.2 J/K = 0.1602 kJ/K
Finally, we calculate the standard Gibbs free energy of the reaction at T = 25°C = 298 K.
ΔG° = ΔH° - T × ΔS°
ΔG° = 179.2 kJ - 298 K × 0.1602 kJ/K
ΔG° = 131.5 kJ
Answer:
One mole of carbon would look like 25/12.01
Explanation:
Firstly, you will divide 25 by 12.01 and get 2.081598
We know 1 mole equals the gram per atomic mass, so one mole of carbon is 12.01 grams. In conclusion, it would look like 25/12.01.
Answer:
All of the above.
Explanation:
In positive deviation from Raoult's Law occur when the vapour pressure of components is greater than what is expected value in Raoult's law.
When a solution is non ideal then it shows positive or negative deviation.
Let two solutions A and B to form non- ideal solutions.let the vapour pressure of component A is 
and vapour pressure of component B is 
.
= Vapour pressure of component A in pure form
= Vapour pressure of component B in pure form
=Mole fraction of component A
=Mole fraction of component B
The interaction between A- B is less than the interaction A- A and B-B interaction.Therefore, the escaping tendency of liquid molecules in mixture is greater than the escaping tendency in pure form.Hence, the vapour pressure of a mixture is greater than the initial value of vapour pressure.
,
Therefore, 
Therefore, the enthalpy of mixing is greater than zero and change in volume is greater than zero.
Hence, option a,b,c and d are true.
Explanation:
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