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ipn [44]
3 years ago
7

The Kw of water varies with temperature. Calculate the pH of water at 46⁰C with a Kw = 1.219 x 10-14. Show all calculations lead

ing to an answer.
Chemistry
1 answer:
stich3 [128]3 years ago
8 0
Kw = 1.219x10⁻¹⁴

kw = [H⁺] x [OH⁻]

in water [H⁺] = [OH⁻] therefore:

[H⁺] = √ kw

[H⁺] = √ <span>1.219x10⁻¹⁴

[H</span>⁺] = 1.104x10⁻⁷

pH = - log [H⁺]

pH = - log [ <span>1.104x10⁻⁷ ]

pH = 6.95

hope this helps!</span>
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Kerosene, a common space-heater fuel, is a mixture of hydrocarbons whose "average" formula is C₁₂H₂₆.
padilas [110]

The calculated enthalpy of formation of kerosene is 365.4 kJ and heat produced is 78650.3 kJ

For this, we need the normal enthalpy of formation given below

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We shall now determine the enthalpy of kerosene formation:

H rxn = 24 mol H f (CO2) + 26 mol H f (H2O) + 2 mol H f (C12H26) + 37 mol H f (O2) + 1.50 104 kJ = 9444 kJ + 6286.8 kJ + 1500 kJ 2 mol H f (C12H26) = 730.8 kJ H f (C12H26) = 365.4 kJ

Kerosene has a density of 0.74 g/mL.

Kerosene volume (V) equals 0.63 gallons, or 0.63 x 3785.4, or 2384. 8 mL.

We shall now calculate the mass (m) of kerosene:

ρ=mVm\s=ρ×Vm\s=0.749g/mL×2384.mLm\s=1786.2g

We shall now discover the heat that 1786 generated.

Two grams of kerosene

Kerosene's molar mass is 170.33 g/mol.

The mass of two moles of kerosene is equal to 2*170.33*340.66g.

1.50104kJ of heat are generated by 340.66 g of kerosene.

1786 produced heat.

Kerosene 2 grams = 1.50 104 kJ 340.66 1786.2 g = 78650.3 kJ

Learn more about enthalpy here-

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