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Marysya12 [62]
3 years ago
8

Recall that the value of Kw for the autoionization of water varies with temperature. At the temperature of your body (37°C), Kw

= 3.98 x 10-14 rather than 1.00 x 10-14. What is the pH of pure water at 37°C?
Chemistry
1 answer:
kvasek [131]3 years ago
5 0

Answer:

pH =6.70

Explanation:

When Kw = 1x10^-14

[H3O+] = [OH-] --> 1x10-7

Kw =3.98x^10-14

3.98x^10-14 = [H3O+] . [OH-]

√ (3.98x^10-14) =  [H3O+] = [OH-]

[H3O+] = 1.99×10^-7

- log [H3O+] = pH ---> -log 1.99x10^-7 = 6.70

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Write Lewis structures for the following molecules: (a) ICl, (b) PH3, (c) P4 (each P is bonded to three other P atoms), (d) H2S,
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Answer :  The Lewis-dot structure for the following molecules are shown below.

Explanation :

Lewis-dot structure : It shows the bonding between the atoms of a molecule and it also shows the unpaired electrons present in the molecule.

In the Lewis-dot structure the valance electrons are shown by 'dot'.

Now we have to determine the Lewis-dot structure for the following molecules.

(a) The given molecule is, ICl

As we know that iodine and chlorine have '7' valence electrons.

Therefore, the total number of valence electrons in ICl = 7 + 7 = 14

According to Lewis-dot structure, there are 2 number of bonding electrons and 12 number of non-bonding electrons.

(b) The given molecule is, PH_3

As we know that phosphorous has '5' valence electrons and hydrogen has '1' valence electrons.

Therefore, the total number of valence electrons in PH_3 = 5 + 3(1) = 8

According to Lewis-dot structure, there are 6 number of bonding electrons and 2 number of non-bonding electrons.

(c) The given molecule is, P_4

As we know that phosphorous has '5' valence electrons.

Therefore, the total number of valence electrons in P_4 = 4(5) = 20

According to Lewis-dot structure, there are 6 number of bonding electrons and 14 number of non-bonding electrons.

(d) The given molecule is, H_2S

As we know that sulfur has '6' valence electrons and hydrogen has '1' valence electrons.

Therefore, the total number of valence electrons in H_2S = 6 + 2(1) = 8

According to Lewis-dot structure, there are 4 number of bonding electrons and 4 number of non-bonding electrons.

(e) The given molecule is, N_2H_4

As we know that nitrogen has '5' valence electrons and hydrogen has '1' valence electrons.

Therefore, the total number of valence electrons in N_2H_4 = 2(5) + 4(1) = 14

According to Lewis-dot structure, there are 10 number of bonding electrons and 4 number of non-bonding electrons.

(f) The given molecule is, HClO_3

As we know that chlorine has '7' valence electrons, oxygen has '6' valence electrons and hydrogen has '1' valence electrons.

Therefore, the total number of valence electrons in HClO_3 = 1 + 7 + 3(6) = 26

According to Lewis-dot structure, there are 12 number of bonding electrons and 14 number of non-bonding electrons.

(g) The given molecule is, COBr_2

As we know that bromine has '7' valence electrons, oxygen has '6' valence electrons and carbon has '4' valence electrons.

Therefore, the total number of valence electrons in COBr_2 = 4 + 6 + 2(7) = 24

According to Lewis-dot structure, there are 8 number of bonding electrons and 16 number of non-bonding electrons.

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