Answer:
Less
Explanation:
Since [Cu(NH3)4]2+ and [Cu(H2O)6]2+ are Octahedral Complexes the transitions between d-levels explain the majority of the absorbances seen in those chemical compounds. The difference in energy between d-levels is known as ΔOh (ligand-field splitting parameter) and it depends on several factors:
- The nature of the ligand: A spectrochemical series is a list of ligands ordered on ligand strength. With a higher strength the ΔOh will be higher and thus it requires a higher energy light to make the transition.
- The oxidation state of the metal: Higher oxidation states will strength the ΔOh because of the higher electrostatic attraction between the metal and the ligand
A partial spectrochemical series listing of ligands from small Δ to large Δ:
I− < Br− < S2− < Cl− < N3− < F−< NCO− < OH− < C2O42− < H2O < CH3CN < NH3 < NO2− < PPh3 < CN− < CO
Then NH3 makes the ΔOh higher and it requires a higher energy light to make the transition, which means a shorter wavelength.
They are called groups or family. Hope this helps
Answer:
The amount of work done on the system is 18234 J and the final positive sign means that this work corresponds to an increase in internal energy of the gas.
Explanation:
Thermodynamic work is called the transfer of energy between the system and the environment by methods that do not depend on the difference in temperatures between the two. When a system is compressed or expanded, a thermodynamic work is produced which is called pressure-volume work (p - v).
The pressure-volume work done by a system that compresses or expands at constant pressure is given by the expression:
W system= -p*∆V
Where:
- W system: Work exchanged by the system with the environment. Its unit of measure in the International System is the joule (J)
- p: Pressure. Its unit of measurement in the International System is the pascal (Pa)
- ∆V: Volume variation (∆V = Vf - Vi). Its unit of measurement in the International System is cubic meter (m³)
In this case:
- p= 10 atm= 1.013*10⁶ Pa (being 1 atm= 101325 Pa)
- ΔV= 2 L- 20 L= -18 L= -0.018 m³ (being 1 L=0.001 m³)
Replacing:
W system= -1.013*10⁶ Pa* (-0.018 m³)
Solving:
W system= 18234 J
<u><em>The amount of work done on the system is 18234 J and the final positive sign means that this work corresponds to an increase in internal energy of the gas.</em></u>
The chemical properties, chemical reactivity
Answer:Could you give a more detailed explanation like what exactly do you need/want?
Explanation:
