In order to find out the ranking of ions basicity, check the
pKa values of each ions. The principle that you need to remember is that the
stronger the acid the weaker the corresponding conjugate base. The pKa dictates
acid value of the compound. The answer would be CH3NH, CH3O-, and CH3CH2-.
Answer : The volume of stock solution needed are, 12.5 mL
Explanation :
Formula used :

where,
are the initial molarity and volume of copper (II) chloride.
are the final molarity and volume of stock solution of copper (II) chloride.
We are given:

Putting values in above equation, we get:

Hence, the volume of stock solution needed are, 12.5 mL
Zeff = Z - S
Here, Z is the number of protons in the nucleus, that is, atomic number, and S is the number of nonvalence electrons.
For boron, the electronic configuration is 1s₂ 2s₂ 2p₄
Z = 5, S = 2
Zeff = 5-2 = +3
For O, electronic configuration is 1s₂ 2s₂ 2p₄
Z = 8, S = 2
Zeff = 8-2 = +6
Hence, the correct answer is second option, that is, +3 and +6, the Zeff of boron is smaller in comparison to O, thus, boron exhibits a bigger size than O.