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The vapor pressure of ethanol is 30°C at 98.5 mmHg and the heat of vaporization is 39.3 kJ/mol. Determine the normal boiling poi

Gelneren [198K]

Answer : The normal boiling point of ethanol will be, $348.67K$ or $75.67^oC$

Explanation :

The Clausius- Clapeyron equation is :

$\ln (\frac{P_2}{P_1})=\frac{\Delta H_{vap}}{R}\times (\frac{1}{T_1}-\frac{1}{T_2})$

where,

$P_1$ = vapor pressure of ethanol at $30^oC$ = 98.5 mmHg

$P_2$ = vapor pressure of ethanol at normal boiling point = 1 atm = 760 mmHg

$T_1$ = temperature of ethanol = $30^oC=273+30=303K$

$T_2$ = normal boiling point of ethanol = ?

$\Delta H_{vap}$ = heat of vaporization = 39.3 kJ/mole = 39300 J/mole

R = universal constant = 8.314 J/K.mole

Now put all the given values in the above formula, we get:

$\ln (\frac{760mmHg}{98.5mmHg})=\frac{39300J/mole}{8.314J/K.mole}\times (\frac{1}{303K}-\frac{1}{T_2})$

$T_2=348.67K=348.67-273=75.67^oC$

Hence, the normal boiling point of ethanol will be, $348.67K$ or $75.67^oC$

3 0

3 years ago

What happens when buoyant mantle material gets near earths surface

krek1111 [17]

It will form mountains, hope this helps

3 0

3 years ago

Read 2 more answers

A 1.2 L weather balloon on the ground has a temperature of 25°C and is at atmospheric pressure (1.0 atm). When it rises to an el

icang [17]

Answer:

The temperature of the air at this given elevation will be 53.32425°C

Explanation:

We can calculate the final temperature through the combined gas law. Therefore we will need to know 1 ) The initial volume, 2 ) The initial temperature, 3 ) Initial Pressure, 4 ) Final Volume, 5 ) Final Pressure.

Initial Volume = 1.2 L ; Initial Temperature = 25°C = 298.15 K ; Initial pressure = 1.0 atm ; Final Volume = 1.8 L ; Final pressure = 0.73 atm

We have all the information we need. Now let us substitute into the following formula, and solve for the final temperature ( T $_2$ ),

P $_1$ V $_1$ / T $_1$ = P $_2$ V $_2$ / T $_2$ ,

T $_2$ = P $_2$ V $_2$ T $_1$ / P $_1$ V $_1$ ,

T $_2$ = 0.73 atm $*$ 1.8 L $*$ 298.15 K / 1 atm $*$ 1.2 L = ( 0.73 $*$ 1.8 $*$ 298.15 / 1 $*$ 1.2 ) K = 326.47425 K,

T $_2$ = 326.47425 K = 53.32425 C

7 0

3 years ago

If a carbon hydrate has 2n possible isomers, where n is equal to the number of carbon atoms in the carbon hydrate structure that

Nataly [62]

Explanation: maybe 1000000

5 0

3 years ago

When NH4NO3 spontaneously dissolves in water the temperature of the solution decreases. What factors make this a naturally occu

erma4kov [3.2K]

Explanation:

Once solid ammonium nitrate interacts with water, the molecules of polar water intermingle with these ions and attract individual ions from the structure of the lattice, that actually will break down. E.g;-NH4NO3(s) — NH4+(aq)+ NO3-(aq) To split the ionic bonds that bind the lattice intact takes energy that is drained from the surroundings to cool the solution.

Some heat energy is produced once the ammonium and nitrate ions react with the water molecules (exothermic reaction), however this heat is far below that is needed by the H2O molecules to split the powerful ionic bonds in the solid ammonium nitrate.

Hence, we can say that the dissolution of ammonium nitrate in water is highly endothermic reaction.

8 0

3 years ago