Question

Which of the following represents a propagation step in the monochlorination of methylene chloride (CH2Cl2)?a. CHCl3 + Cl. Right arrow .CCl3 + HCl.b. CHCl2 + Cl2 right arrow CHCl3 + Cl..c. CH2Cl + Cl2 right arrow CH2Cl2 + Cl..d. CHCl2 + Cl. Right arrow CHCl3

Answer 1

Answer:

B = CHCl2 + Cl2 --> CHCl3 + Cl

Explanation:

Free radical halogenation is a chlorination reaction on Alkane hydrocarbons. This involves the splitting of molecules into radicals/ unstable molecules in the presence of sunlight/ U.V light which ensures bonding of the molecules.

Free radical chlorination is divided into 3 steps which are:

The initiation step

The propagation step

The termination step

So in reference to the question, propagation step involves two steps.

The first step is where the molecule in this case the methylene chloride(CH2Cl2) loses a hydrogen atom and then bond with a chlorine atom radical to give a nethylwnw chloride radical and HCl.

The second step involves the reaction of this methylene chloride got in the first step with chlorine molecule to form trichloride methane and a chlorine radical.

You would find in the attachment the 2 step mechanism.