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notsponge [240]
2 years ago
7

For the following reaction, 4.31 grams of iron are mixed with excess oxygen gas . The reaction yields 5.17 grams of iron(II) oxi

de . iron ( s ) + oxygen ( g ) iron(II) oxide ( s ) What is the theoretical yield of iron(II) oxide ? 21.6 grams What is the percent yield for this reaction ? 85 %
Chemistry
1 answer:
natka813 [3]2 years ago
7 0

<u>Answer:</u> The theoretical yield of iron (II) oxide is 5.53g and percent yield of the reaction is 93.49 %

<u>Explanation:</u>

To calculate the number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}       ....(1)

  • <u>For Iron:</u>

Given mass of iron = 4.31 g

Molar mass of iron = 53.85 g/mol

Putting values in above equation, we get:  

\text{Moles of iron}=\frac{4.31g}{53.85g/mol}=0.0771mol

For the given chemical reaction:

2Fe(s)+O_2(g)\rightarrow 2FeO(s)

By Stoichiometry of the reaction:

2 moles of iron produces 2 moles of iron (ii) oxide.

So, 0.0771 moles of iron will produce = \frac{2}{2}\times 0.0771=0.0771mol of iron (ii) oxide

Now, calculating the theoretical yield of iron (ii) oxide using equation 1, we get:

Moles of of iron (II) oxide = 0.0771 moles

Molar mass of iron (II) oxide = 71.844 g/mol

Putting values in equation 1, we get:  

0.0771mol=\frac{\text{Theoretical yield of iron(ii) oxide}}{71.844g/mol}=5.53g

To calculate the percentage yield of iron (ii) oxide, we use the equation:

\%\text{ yield}=\frac{\text{Experimental yield}}{\text{Theoretical yield}}\times 100

Experimental yield of iron (ii) oxide = 5.17 g

Theoretical yield of iron (ii) oxide = 5.53 g

Putting values in above equation, we get:

\%\text{ yield of iron (ii) oxide}=\frac{5.17g}{5.53g}\times 100\\\\\% \text{yield of iron (ii) oxide}=93.49\%

Hence, the theoretical yield of iron (II) oxide is 5.53g and percent yield of the reaction is 93.49 %

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Answer:

a) ΔHºrxn = 116.3 kJ, ΔGºrxn = 82.8 kJ,  ΔSºrxn =  0.113 kJ/K

b) At 753.55 ºC or higher

c )ΔG =  1.8 x 10⁴ J

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Explanation:

a)                                 C6H5−CH2CH3  ⇒  C6H5−CH=CH2  + H₂

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Sº J/mol                          255                          238                      130.6*

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Using Hess law to calculate  ΔHºrxn we have

ΔHºrxn  = ΔHfº C6H5−CH=CH2 +  ΔHfº H₂ - ΔHºfC6H5−CH2CH3

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we see that will happen when the term  TΔS  becomes greater than ΔHrxn since ΔS  is positive  , and so to sollve for T we will make ΔGrxn equal to zero and solve for T. Notice here we will make the assumption that  ΔºHrxn and ΔSºrxn remain constant at the higher temperature  and will equal the values previously calculated for them. Although this assumption is not entirely correct, it can be used.

0 = 116 kJ -T (0.113 kJ/K)

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